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  1. 1

    The wide range of battery systems: From micro- to structural batteries, from biodegradable to high performance batteries

    Publicação
    por Costa, Carlos Miguel Silva
    Outros Autores: Salado, Manuel; Ferrara, Chiara; Ruffo, Riccardo; Mustarelli, Piercarlo; Mao, Rui et al.
    Battery systems are essential components of the on-going energy transition and digitalization of society. With the need to power an increasing variety of portable and stationary systems, ranging from disposable point-of-care devices or smart packaging systems to applications in portable computers and electric cars, an increasing variety of batteries and battery systems are being developed, each aiming to specific sets of required performance parameters, including energy and power density, cycling stability, flexibility, degradability, environmental impact or improved integration into the specific application context. This work analyzed the state of the art of the different materials and geometries, performance parameters and applications of the different battery systems. We discuss the rationale behind each material selection, the processing technologies and the integration into the specific application, taking into account the whole life-cycle of the battery. Further, the main challenges posed for each battery type will provide a roadmap for their successful development and application.
    2025 artigo Portugal acesso aberto
  2. 2

    Development and characterisation of cytocompatible polyester substrates with tunable mechanical properties and degradation rate

    Publicação
    por Ribeiro, Sofia
    Outros Autores: Carvalho, Ana M.; Fernandes, Emanuel Mouta; Gomes, Manuela E.; Reis, R. L.; Bayon, Yves et al.
    Although it has been repeatedly indicated the importance to develop implantable devices and cell culture substrates with tissue-specific rigidity, current commercially available products, in particular cell culture substrates, have rigidity values well above most tissues in the body. Herein, six resorbable polyester films were fabricated using compression moulding with a thermal presser into films with tailored stiffness by appropriately selecting the ratio of their building up monomers (e.g. lactide, glycolide, trimethylene carbonate, dioxanone, ε-caprolactone). Typical NMR and FTIR spectra were obtained, suggesting that the fabrication process did not have a negative effect on the conformation of the polymers. Surface roughness analysis revealed no apparent differences between the films as a function of polymer composition. Subject to polymer composition, polymeric films were obtained with glass transition temperatures from -52 °C to 61 °C; contact angles in water from 81 ° to 94 °; storage modulus from 108 MPa to 2,756 MPa and loss modulus from 8 MPa to 507 MPa (both in wet state, at 1 Hz frequency and at 37 °C); ultimate tensile strength from 8 MPa to 62 MPa, toughness from 23 MJ/m3 to 287 MJ/m3, strain at break from 3 % to 278 %, macro-scale Young's modulus from 110 MPa to 2,184 MPa (all in wet state); and nano-scale Young's modulus from 6 kPa to 15,019 kPa (in wet state). With respect to in vitro degradation in phosphate buffered saline at 37 °C, some polymeric films [e.g. poly(glycolide-lactide) 30 / 70] started degrading from day 7 (shortest timepoint assessed), whilst others [e.g. poly(glycolide-co-ε-caprolactone) 10 / 90] were more resilient to degradation up to day 21 (longest timepoint assessed). In vitro biological analysis using human dermal fibroblasts and a human monocyte cell line (THP-1) showed the potential of the polymeric films to support cell growth and controlled immune response. Evidently, the selected polymers exhibited properties suitable for a range of clinical indications.
    2021 artigo Portugal acesso aberto