On the O2(v')+O2(v'') atmospheric reaction. II. The role of rotational excitation

• Autor(es): Wang, W. ; C. Varandas, A. J.
• Data: 1998
• Identificador Persistente: https://hdl.handle.net/10316/5279
• Origem: Estudo Geral - Universidade de Coimbra
• Tipo de Documento: Artigo científico
• Idioma: Inglês

Descrição

The effect of rotational excitation on the rate constant for the title reaction is investigated by using the quasiclassical trajectory method and the realistic double many-body expansion (DMBE) potential energy surface for ground-state triplet O4. The results are compared with previously reported calculations in which such effects have been neglected.

http://www.sciencedirect.com/science/article/B6TFM-3VM1TCN-J/1/d430a40e12ae9f4d22b6b727a4cda2da