Leaching behavior of several zinc rich residues in a hydrometallurgical recycling process

• Author(s): Pedrosa, Fátima ; Cabral, Marta ; Nogueira, Carlos ; Margarido, F.
• Date: 2009
• Persistent ID: http://hdl.handle.net/10400.9/590
• Origin: Repositório do LNEG
• Subject(s): Zinc residues; Spent batteries; EAF dusts; Recycling; Leaching
• Document Type: Conference object
• Language: English
• Contributor(s): Repositório do LNEG

Description

The leaching of metals contained in spent Zn-MnO2 batteries and electric arc furnace (EAF) dusts using sulfuric acid solutions was studied, in order to evaluate the feasibility of simultaneous treatment of both wastes by a hydrometallurgical process. In both residues, a substantial quantity of zinc was solubilized (about 100% in batteries and 70-80% in EAF dusts) in diluted acid solutions and room temperature, corresponding to the reaction of zinc oxide species. Other species were more refractory to the chemical attack, namely the manganese (III or IV) oxides in batteries and the zinc ferrite in dusts, requiring higher temperatures (e.g. 90ºC) and higher leachant concentrations. Lead present in EAF dusts was not solubilized in sulfate media, thus remaining in the leach residue. Results seem to confirm the possibility of treatment of both zinc-containing residues by the same hydrometallurgical process, eventually involving two leaching stages – diluted acid leaching and hot acid leaching – followed by solution purification through iron precipitation and Zn/Mn separation and recovery. Concerning lead, a second leaching circuit in chloride media could be developed for its potential recovery.