Document details

Cobalt selenate pentahydrate: Thermal decomposition intermediates and their properties dependence on temperature changes

Author(s): de Godoi Machado, Rafael [UNESP] ; Gaglieri, Caroline [UNESP] ; Alarcon, Rafael Turra [UNESP] ; de Moura, Aniele [UNESP] ; de Almeida, Amanda Cosmo [UNESP] ; Caires, Flávio Junior [UNESP] ; Ionashiro, Massao [UNESP]

Date: 2020

Persistent ID: http://hdl.handle.net/11449/201710

Origin: Oasisbr

Subject(s): Color dependence; Dehydration process; Selenate materials; Temperature effect


Description

Made available in DSpace on 2020-12-12T02:39:49Z (GMT). No. of bitstreams: 0 Previous issue date: 2020-07-01

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Several new materials based on selenates and selenites have been produced, characterized and their application have exhibited good results in several areas. As consequence, some selenates/selenites that had been synthetized in the past have been better characterized aiming to provide more information about their properties to be applied. Thus, this work aims to provide a deep investigation about cobalt selenate pentahydrate focusing in its thermal behavior and in the properties of its thermal intermediates. To achieve this goal were used Simultaneous Thermogravimetry-Differential Thermal Analysis and Differential Scanning Calorimetry were used to determine the thermal properties; Furthermore, X-ray Powder Diffraction helped to confirm the crystallographic phase of each one and the morphological properties were studied using Scanning Electronic Microscopy. Lastly, the Ultra Violet-Visible/Near infrared spectroscopy together with the microscopy-Differential Scanning Calorimetry results elucidated the effect of the electronical changes on observed color. All these changes were related to the temperature.

UNESP- São Paulo State University School of Sciences Chemistry Department

UNESP- São Paulo State University Institute of Chemistry

UNESP- São Paulo State University School of Sciences Chemistry Department

UNESP- São Paulo State University Institute of Chemistry

CAPES: 024/2012

FAPESP: 2017/14936-9

FAPESP: 2018/03460-6

FAPESP: 2018/24378-6

CNPq: 421469/2016-1

Document Type Journal article
Language English
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