Detalhes do Documento

Application of Mixture Design and Kohonen Neural Network for Determination of Macro- and Microelement in Mullet (Mugil cephalus) by MIP OES

Autor(es): Viana Pacheco, Clissiane Soares ; Costa, Floriatan Santos ; Guedes, Wesley Nascimento [UNESP] ; Jesus, Marina Santos de ; das Chagas, Thiago Pereira ; Pinto dos Santos, Ana Maria ; Lima, Daniel de Castro ; Paranhos da Silva, Erik Galvao

Data: 2021

Identificador Persistente: http://hdl.handle.net/11449/209115

Origem: Oasisbr

Assunto(s): Mugil cephalus; Mixture design; Kohonen self-organizing map; MIP OES


Descrição

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Fundacao de Amparo a Pesquisa do Estado da Bahia (FAPESB)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

In this study, the concentrations of macro- and microelement in different tissues (liver, gill, and muscle) of fish collected (Mugil cephalus) in Pontal Bay (Ilheus, Bahia) were determined. A simplex-centroid mixture design was used to obtain the mixture applied to the decomposition of the samples. The elementary determination was made by microwave-induced plasma optical emission spectrometry (MIP OES), and the Kohonen self-organizing map (KSOM) was applied as an exploratory analysis tool. The accuracy of the procedure was assessed using certified reference material. Recoveries were obtained in the range of 99-103% and without a statistical difference (95% confidence level). Precision was estimated from the relative standard deviation, which ranged from 0.3 to 2.2%, and the limits of detection (mg kg(-1)) were 0.145 (Cu), 1.53 (Fe), 1.61 (K), 0.250 (Mg), 0.040 (Mn), 4.84 (P), and 2.12 (Zn). The KSOM provided efficient and precise separation of the studied tissues into three groups. The concentrations of Cu, Fe, and Zn were higher in the liver, while in the gills, they were the Mn.

Univ Fed Bahia, Inst Chem, BR-40170290 Salvador, BA, Brazil

Univ Fed Parana, Dept Chem, BR-81530900 Curitiba, Parana, Brazil

Univ Estadual Paulista, Inst Chem, BR-14800060 Araraquara, SP, Brazil

Univ Estadual Santa Cruz, Dept Exact & Technol Sci, BR-45662900 Ilheus, BA, Brazil

Univ Estadual Paulista, Inst Chem, BR-14800060 Araraquara, SP, Brazil

CNPq: 306698/2019-6

CNPq: 421694/2018-1

CAPES: 001

Tipo de Documento Artigo científico
Idioma Inglês
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