Document details

A multi-metal risk assessment strategy for natural freshwater ecosystems based on the additive inhibitory free metal ion concentration index

Author(s): Alves, Cristina M. ; Ferreira, Carlos M. H. ; Soares, Eduardo V. ; Soares, Helena M. V. M.

Date: 2017

Persistent ID: https://hdl.handle.net/1822/44931

Origin: RepositóriUM - Universidade do Minho

Project/scholarship: info:eu-repo/grantAgreement/FCT/5876/147218/PT; info:eu-repo/grantAgreement/FCT/5876/147337/PT; info:eu-repo/grantAgreement/FCT/5876-PPCDTI/126270/PT ; info:eu-repo/grantAgreement/FCT/COMPETE/126270/PT;

Subject(s): Additive inhibitory metal concentration index (AIMCi); Alga; Chronic toxicity assay; Metal speciation; Metal bioavailability; Science & Technology


Description

Scientifically sound risk assessment strategies and derivations of environmental quality standards for metals present in freshwater environments are currently hampered by insufficient chronic toxicity data collected from natural ecosystems, as well as inadequate information on metal speciation. Thus, the aim of the present study was to evaluate the impact of freshwater containing multiple metals (Cd, Cr, Cu, Ni, Pb and Zn) on the chronic toxicity (72h) to the alga Pseudokirchneriella subcapitata and compare the observed toxicity results to the total and free metal concentration of the samples. Based on the information obtained herein, an additive inhibitory free multi-metal ion concentration index, calculated as the sum of the equivalent toxicities to the free metal ion concentration of each sample, was developed. The proposed index was well correlated to the observed chronic toxicity results, indicating that the concentration addition, when expressed as the free-ion activity, can be considered a reliable indicator for the evaluation of ecological risk assessments for natural waters containing multiple metals.

This work was performed in the framework of the financing with references LAQV (UID/QUI/50006/2013 - POCI/01/0145/FEDER/007265) and UID/BIO/04469/2013 - POCI-01-0145-FEDER-006684 with financial support from FCT/MEC through national funds and co-financed by FEDER, under the Partnership Agreement PT2020 and Project RECI/BBB-EBI/0179/2012 (FCOMP-01-0124-FEDER-027462).

Document Type Journal article
Language English
Contributor(s) Universidade do Minho
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