Author(s): Moniz, Mariana P. ; Rafique, Amjid ; Carmo, João ; Oliveira, J. P. ; Marques, Ana ; Ferreira, Isabel M. M. ; Baptista, Ana Catarina
Date: 2023
Persistent ID: http://hdl.handle.net/10362/158330
Origin: Repositório Institucional da UNL
Subject(s): electronic textiles; electrospray; flexible supercapacitors; gel-polymer electrolyte; PEDOT:PSS; Materials Science(all)
Funding Information: This work was financed by national funds from FCT─Fundação para a Ciência e a Tecnologia, I.P., in the scope of the All-FIBRE project with the reference PTDC/CTM-CTM/1571/2020, and the projects LA/P/0037/2020, UIDP/50025/2020, and UIDB/50025/2020 of the Associate Laboratory Institute of Nanostructures, Nanomodelling, and Nanofabrication─i3N. This work was also supported by ERC-CoG-2014, CapTherPV, 647596. The authors would like to thank Professor Daniela Gomes from CENIMAT for the SEM images. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.
The increasing demand for flexible electronic devices has risen due to the high interest in electronic textiles (e-textiles). Consequently, the urge to power e-textiles has sparked enormous interest in flexible energy storage devices. One-dimensional (1D) configuration supercapacitors are the most promising technology for textile applications, but often their production involves complex synthesis techniques and expensive materials. This work unveils the use of the novel electrospray deposition (ESD) technique for the deposition of poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT:PSS). This deposition methodology on conductive carbon yarns creates flexible electrodes with a high surface area. The deposition conditions of PEDOT:PSS were optimized, and their influence on the electrochemical performance of a 1D symmetric supercapacitor with a cellulose-based gel as an electrolyte and a separator was evaluated. The tests herein reported show that these capacitors exhibited a high specific capacitance of 72 mF g-1, an excellent cyclability of more than 85% capacitance retention after 1500 cycles, and an outstanding capability of bending.
