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Thermal stability and decomposition kinetics of NdNiO3− δ at 1 bar of O2

Bassou, A. A.; Machado, P. J.; Gomes, M. M.; Manjunath, B.; Vilarinho, R.; Silva, Bruna Andreia Nogueira Airosa; Oliveira, José A.; Almeida, B. G.

Despite the interest in rare-earth nickelates for applications, their processing under 1 bar of oxygen pressure is still challenging. In this work, we report the co-precipitation synthesis, thermal stability and thermally driven decomposition of NdNiO3 phase, in order to determine the synthesis parameters towards a pure perovskite phase. We concluded that using a 1% molar excess of Nd during preparation and pos...


Deposition of Lu-Fe-O thin films on silica glass substrates by MOCVD

Cardoso, A. F.; Bassou, A. A.; Amaral, V. S.; Fernandes, J. R.; Tavares, Pedro

Thin films of the Lu-Fe-O system were deposited by aerosol assisted MOCVD on silica glass substrates. Hexagonal h-LuFeO3, garnet Lu3Fe5O12, perovskite o-LuFeO3 or hematite Fe2O3 phases were obtained, depending on the thermodynamic deposition conditions or post annealing temperature. Magnetic measurements confirm the ferromagnetic behaviour at room temperature of the thin films with garnet phase. An indirect ban...

Date: 2020   |   Origin: Repositório da UTAD

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