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Syntheses, crystal structure and spectroscopic characterization of new platinum...
Amim, Raquel S.; Oliveira, Marcelo Ribeiro Leite; Perpétuo, Genivaldo Julio; Janczak, Jan; Miranda, Liany Divina LimaThe reaction of 4-iodobenzenesulfonamide or 4-fluorobenzenesulfonamide with CS2 and KOH in dimethylformamide yielded the potassium N-R-sulfonyldithiocarbimates, K2(RSO2N@CS2) [R = 4-IC6H4 (1) and 4-FC6H4 (2)]. These salts reacted with K2[PtCl4] in water/methanol to yield complex anions bis(N-R-sulfonyldithiocarbimato) platinate(II), which were isolated as their tetrabutylammonium salts, (Bu4N)2[Pt(RSO2N@CS2)2] ...
Date: 2015
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Origin: Oasisbr