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From PEF to PBF: what difference does the longer alkyl chain make a computation...
Nolasco, Mariela M.; Rodrigues, Leonor C.; Araújo, Catarina F.; Coimbra, Mariana M.; Ribeiro-Claro, Paulo; Vaz, Pedro D.; Rudić, SvemirThis work explores the conformational preferences and the structureproperty correlations of poly(butylene 2,5-furandicarboxylate) (PBF), a longer chain analogue of the most well-known biobased polyester from the furan family, poly(ethylene 2,5-furandicarboxylate) (PEF). A thorough computational spectroscopic study–including infrared, Raman and inelastic neutron scattering spectroscopy, combined with discrete an...
Isosorbide and 2,5-Furandicarboxylic Acid Based (Co)Polyesters: Synthesis, Char...
Bouyahya, Chaima; Patrício, Rafael; Paço, Ana; Lima, Mafalda S.; Fonseca, Ana C.; Rocha-Santos, Teresa; Majdoub, Mustapha; Silvestre, Armando J.D.Poly(2,5-furandicarboxylate)s incorporating aliphatic moieties represent a promising family of polyesters, typically entirely based on renewable resources and with tailored properties, notably degradability. This study aims to go beyond by developing poly(isosorbide 2,5-furandicarboxylate-co-dodecanedioate) copolyesters derived from isosorbide (Is), 2,5-furandicarboxylic acid (FDCA), and 1,12-dodecanedioic acid...