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Phthalocyanine thio-pyridinium derivatives as antibacterial photosensitizers

Pereira, Joana B.; Carvalho, Eliana F. A.; Faustino, Maria A. F.; Fernandes, Rosa; Neves, Maria G. P. M. S.; Cavaleiro, José A. S.; Gomes, Newton C. M.

This study describes the synthesis of three new tetra- and octa-thio-pyridinium phthalocyanine derivatives. PSs 3a and 4a were prepared from the tetramerization of phthalonitriles 1 and 2, respectively, whereas PS 5 was prepared from the nucleophilic substitution of the 8 beta fluor atoms of hexadecafluorophthalocyaninatozinc(II) by mercaptopyridine, followed by cationization. The recombinant bioluminescent Esc...


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