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Grain boundary corrosion in TiO2 bone scaffolds doped with group II cations

Klemm, A.; Gomez-Florit, Manuel; Carvalho, P. A.; Wachendörfer, M.; Gomes, Manuela E.; Haugen, H. J.; Tiainen, H.

A pH drop during the inflammatory phase during bone regeneration can cause corrosion in TiO2 bone scaffolds and the loss of compressive strength. Corrosion as ion leaching and dissolution is confined to grain boundaries. Cationic doping of TiO2 showed to increase the compressive strength but increased the amount of impurities in grain boundaries as well. Therefore, this study showed the different grain boundary...


Characterization of enamel surface after orthodontic brackets debonding: an in ...

Peixoto, A.; Mesquita, M. F.; Costa, H. N.; Carvalho, P. A.; Manso, A.


Pozzolanic activity of oil-refining catalyst: evaluation by electron and atomic...

Jeremias, J.; Nogueira, I.; Nolasco, P.; Carvalho, P. A.; Ferreira, C.; Costa, Carla

The reuse of waste fluid catalytic cracking (FCC) catalyst as partial surrogate for cement can reduce the environmental impact of both the oil-refinery and cement production industries [1,2]. FCC catalysts can be considered as pozzolanic materials since in the presence of water they tend to chemically react with calcium hydroxide to produce compounds possessing cementitious properties [3,4]. In addition, partia...


Emissions of nanoparticles during friction stir welding (FSW) of aluminium alloys

Gomes, João; Miranda, R. M.; Santos, T. J. G.; Carvalho, P. A.

Friction stir welding (FSW) is now well established as a welding process capable of joining some different types of metallic materials, as it was (1) found to be a reliable and economical way of producing high quality welds, and (2) considered a "clean" welding process that does not involve fusion of metal, as is the case with other traditional welding processes. The aim of this study was to determine whether t...


The effect of metal transfer modes and shielding gas composition on the emissio...

Gomes, João; Miranda, R. M.; Carvalho, P. A.; Quintino, M. L.

The present study aims to characterize ultrafine particles emitted during gas metal arc welding of mild steel and stainless steel, using different shielding gas mixtures, and to evaluate the effect of metal transfer modes, controlled by both processing parameters and shielding gas composition, on the quantity and morphology of the ultrafine particles. It was found that the amount of emitted ultrafine particles ...


Characterization of enamel surface after orthodontic brackets debonding: an in ...

Peixoto, A.; Mesquita, M. F.; Costa, H. N.; Carvalho, P. A.; Manso, A.


Microscopy: a tool for quantitative pozzolanic activity in blended cements

Costa, Carla; Laginha, I.; Carvalho, P. A.

In the present study waste FCC catalyst has been incorporated in cement paste mortars with a 15:85 weight ratio. The microstructural evolution of the blended materials has been investigated by X-ray diffraction and scanning electron microscopy coupled with X-ray energy dispersive spectroscopy after curing times of 2, 7 and 28 days. Namely, the evolutions of the catalyst crystal structure and of the calcium cont...


Blistering of W-Ta composites at different irradiation energies

Mateus, R.; Dias, M.; Lopes, J.; Rocha, J.; Catarino, N.; Duarte, P.; Gomes, R. B.; Silva, C.; Fernandes, H.; Livramento, V.; Carvalho, P. A.; Alves, E.

Pure tungsten and tantalum plates and tungsten-tantalum composites produced via mechanical alloying and spark plasma sintering were bombarded with He+ and D+ energetic ion beams and deuterium plasmas. The aim of this experiment is to study the effects caused by individual helium and deuterium exposures and to evidence that the modifications induced in the composites at different irradiation energies could be fo...


An SEM investigation of the pozzolanic activity of a waste catalyst oil refinery

Costa, Carla; Marques, Paulo; Carvalho, P. A.

The most active phase of the fluid catalytic cracking (FCC) catalyst, used in oil refinery, is zeolite-Y which is an aluminosilicate with a high internal and external surface area responsible for its high reactivity. Waste FCC catalyst is potentially able to be reused in cement-based materials - as an additive - undergoing a pozzolanic reaction with calcium hydroxide (Ca(OH)2) formed during cement hydration [1-...


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