10 documents found, page 1 of 1

Editorial: Women in chemistry 2022

Biological consequences of Vanadium effects on formation of reactive oxygen spe...

Lipid peroxidation (LPO), a process that affects human health, can be induced by exposure to vanadium salts and compounds. LPO is often exacerbated by oxidation stress, with some forms of vanadium providing protective effects. The LPO reaction involves the oxidation of the alkene bonds, primarily in polyunsaturated fatty acids, in a chain reaction to form radical and reactive oxygen species (ROS). LPO reactions...

Polyoxidovanadates' interactions with proteins: an overview

Polyoxidovanadates (POVs, previously named polyoxovanadates) are a subgroup of polyoxidometalates (POMs, previously named polyoxometalates) with interesting pharmacological actions that have been tested as potential antidiabetic, antibacterial, antiprotozoal, antiviral, and anticancer drugs. They contain mainly vanadium and are able to interact with proteins, affecting various biological processes. The most stu...

Polyoxovanadates with emerging biomedical activities

Polyoxovanadates (POVs) are a subclass of a larger family of polyanionic group V and VI metal-oxo clus ters that are known as polyoxometalates (POMs). POMs have been found to have antidiabetic, antibacte rial, antiprotozoal, antiviral and anticancer activities, which have sparked interest in their use as bioinorganic drugs. Among POVs, decavanadate ([V10O28] 6 ; V10) is an isopolyoxovanadate recently described ...

Interaction of decavanadate with interfaces and biological modelmembranesystems...

Decavanadate is a polyoxometalate consisting of 10 octahedral vanadium centers, which has been found to exert biological effects and has been observed in vivo. Biological activity implies that a material is taken up into a cell or that the material interacts with membrane receptors. Because of the large size and the high molecular charge, it is nontrivial to anticipate how such a large anion interacts with memb...

Decavavanadate (V10 O6-28) and oxovanadates: oxometalates with many biological ...

The decameric vanadate species V10O6 28 , also referred to as decavanadate, impact proteins, lipid structures and cellular function, and show some effects in vivo on oxidative stress processes and other biological properties. The mode of action of decavanadate in many biochemical systems depends, at least in part, on the charge and size of the species and in some cases competes with the simpler oxovanadate spec...

Effects of decavanadate and insulin enhancing vanadium compounds on glucose upt...

The effects of different vanadium compounds namely pyridine-2,6-dicarboxylatedioxovanadium(V) (V5-dipic), bis(maltolato) oxovanadium(IV) (BMOV) and amavadine, and oligovanadates namely metavanadate and decavanadate were analysed on basal and insulin stimulated glucose uptake in rat adipocytes. Decavanadate (50 lM), manifest a higher increases (6-fold) on glucose uptake compared with basal, followed by BMOV (1 m...

Sarcoplasmic reticulum calcium ATPase is inhibited by organic vanadium coordina...

Inorg Chem. 2008 Jul 7;47(13):5677-84. doi: 10.1021/ic702405d; The general affinity of the sarcoplasmic reticulum (SR) Ca (2+)-ATPase was examined for three different classes of vanadium coordination complexes including a vanadium(V) compound, pyridine-2,6-dicarboxylatodioxovanadium(V) (PDC-V(V)), and two vanadium(IV) compounds, bis(maltolato)oxovanadium(IV) (BMOV), and an analogue of amavadine, bis( N-hydroxyl...

Sarcoplasmic reticulum calcium ATPase is inhibited by organic vanadium coordina...

The general affinity of the sarcoplasmic reticulum (SR) Ca2+-ATPase was examined for three different classes of vanadium coordination complexes including a vanadium(V) compound, pyridine-2,6-dicarboxylatodioxovanadium(V) (PDC-V(V)), and two vanadium(IV) compounds, bis(maltolato)oxovanadium(IV) (BMOV), and an analogue of amavadine, bis(N-hydroxylamidoiminodiacetato)vanadium(IV) (HAIDA-V(IV)). The ability of vana...

Spectrometric and electrochemical investigation of vanadium(V) and vanadium(IV)...

Os complexos de vanádio(IV) e (V) com tartarato formados em solução e as suas possíveis interconversões foram estudados utilizando-se técnicas espectroscópicas e eletroquímicas. A investigação foi feita através de espectroscopia de NMR de 51V combinada com 1H, de NMR de 13C e espectroscopia de EPR. Como técnicas electroquímicas utilizaram-se a polagrografia e a voltametria cíclica. Verificou-se que complexo que...