128 documents found, page 1 of 13
Selective biphasic oxidation of nitrogenated contaminants with H2O2 using polyo...
Roman, Fernanda; Piccinin, Larissa; Silva, Adriano S.; Díaz de Tuesta, Jose Luis; Vieira, Admilson L.; Silva, Adrián; Faria, Joaquim; Gomes, HelderLiquid/liquid biphasic oxidations are extensively employed in the chemical industry to manufacture a variety of chemicals and for environmental issues, such as the oxidative denitrogenated (ODN) and desulfurization of fuels. The ubiquitous presence of nitrogenated and sulfonated compounds in petroleum-derived fuels is associated with environmental and health issues, driving legislation to become stricter regard...
Response surface method-driven design of experiments for the synthesis of fly a...
Silva, Ana P. F.; Natal, Ana Paula Silva; Baldo, Arthur Pietrobon; Silva, Adriano S.; Díaz de Tuesta, Jose Luis; Marin, Pricila; Peres, José A.The growing need for sustainable wastewater treatment solutions has led to exploring alternative materials to explore large-scale and reliable technologies. This study focuses on optimizing the synthesis of geopolymers based on fly ash using a Box-Behnken experimental design to enhance their adsorption efficiency for phenolic compounds, as gallic acid model pollutant which are widely found in wastewater leachin...
Plastic waste-derived carbon nanotubes: Influence of growth catalyst and cataly...
Roman, Fernanda; Silva, Adriano S.; Díaz de Tuesta, Jose Luis; Baldo, Arthur Pietrobon; Lopes, Jéssica Paula Marim; Gonçalves, Giane; Pereira, Ana I.Low-density polyethylene (LDPE) was used in this work to grow carbon nanotubes (CNTs) by chemical vapor deposition (CVD) over catalysts based on Ni, Fe and Al, synthesized either by co-precipitation (C) or wet impregnation (I) methods, with CNT yields in the range of 16–33 %. The morphology of the CNTs was directly influenced by the route used for the CVD catalyst synthesis, with co-precipitation-derived CVD ca...
Occurrence of micropollutants in surface water and removal by catalytic wet per...
Silva, Adriano S.; Zadra Filho, Paulo Cesar; Ferreira, Ana Paula; Roman, Fernanda; Baldo, Arthur Pietrobon; Rauhauser, MadeleineMonitoring campaigns of contaminants of emerging concern (CECs) in surface waters is of utmost importance in evaluating the anthropogenic impact on riparian ecosystems. Beyond identifying pollutants and threats, treatment solutions are also needed to mitigate the adverse effects caused by polluted water discharged into the environment. For years, grab samples have been used to assess water quality, but the resu...
Growth of Carbon Nanotubes on Co(x)‐Ni(1‐x) Ferrites by Chemical Vapor Depositi...
Silva, Adriano S.; Roman, Fernanda; Díaz de Tuesta, Jose Luis; Olias, Lola G.; Çaha, Ihsan; Ferreira, Ana P.; Souza, Renata P. deUpcycling plastic solid wastes (PSWs) into high-value carbon nanotubes (CNTs) offers a promising approach to sustainable material development. This study explores the synthesis of CNTs via chemical vapor deposition (CVD) using mixed cobalt-nickel-iron oxide catalysts supported on alumina and PSW representative polyolefins as carbon sources. The impact of catalyst composition on the yield, morphology, and textur...
The Composting of Water Hyacinth: A Life Cycle Assessment Perspective
Serafini, Lais Fabiana; Arrobas, Margarida; Rodrigues, Manuel Ângelo; Feliciano, Manuel; Miguens, Filomena; Oliveira, Verónica; Santos, DanielaWater hyacinth is an invasive species that causes eutrophication in lentic waters. While mechanical removal is effective, it generates hazardous waste with biological contamination risk. Composting is a safe waste treatment option, inhibiting seeds and yielding agriculturally suitable compost. Life cycle assessment evaluated the environmental impacts of six composting piles using eight different by-products (po...
3D printed photopolymer derived carbon catalysts for enhanced wet peroxide oxid...
Silva, Adriano S.; Díaz de Tuesta, Jose Luis; Henrique, Adriano; Roman, Fernanda; Omralinov, Daria; Steldinger, Hendryk; Gläsel, JanIn this paper, we explore the application of powdered carbon and 3D-printed carbon monoliths prepared by carbonization of a tailored photopolymer. We demonstrate the efficiency of the developed carbonaceous samples in removing paracetamol (PCM) and sulfamethoxazole (SMX), used as model contaminants. Our results demonstrate that carbon samples are active in CWPO, and their catalytic activity is significantly imp...
Removal of gaseous ammonia released from leachate by adsorption on carbon-based...
Perdigão-Lima, Thalles; Díaz de Tuesta, Jose Luis; Feliciano, Manuel; Furst, Leonardo; Roman, Fernanda; Silva, Adriano S.; Pereira Wilken, Adriana A.Landfill facilities and organic waste treatment plants typically are known sources of odour pollution, such as gaseous NH3, among others. In this work, the removal of gaseous NH3 released from a composting line of a mechanical and biological treatment plant of undifferentiated municipal solid waste was assessed in a fixed-bed column loaded with carbon-based adsorbents (CBAs) prepared from olive stone and malt b...
The Composting of Water Hyacinth: A Life Cycle Assessment Perspective
Serafini, Laís Fabiana; Arrobas, Margarida; Rodrigues, M.A.; Feliciano, Manuel; Miguens, Filomena; Oliveira, Verónica; Santos, DanielaWater hyacinth is an invasive species that causes eutrophication in lentic waters. While mechanical removal is effective,it generates hazardous waste with biological contamination risk. Composting is a safe waste treatment option, inhibiting seeds and yielding agriculturally suitable compost. Life cycle assessment evaluated the environmental impacts of six composting piles using eight different by-products (pot...
Deep Learning-Based Classification and Quantification of Emulsion Droplets: A Y...
Mendes, João; Silva, Adriano S.; Roman, Fernanda; Díaz de Tuesta, Jose Luis; Lima, José; Gomes, Helder; Pereira, Ana I.This study focuses on the analysis of emulsion pictures to understand important parameters. While droplet size is a key parameter in emulsion science, manual procedures have been the traditional approach for its determination. Here we introduced the application of YOLOv7, a recently launched deep-learning model, for classifying emulsion droplets. A comparison was made between the two methods for calculating dro...