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N,N'-Ethylenebis(pyridoxylideneiminato) and N,N'-Ethylenebis(pyridoxylaminato):...

Correia, Isabel; Pessoa, João Costa; Duarte, M. Teresa; Henriques, Rui T.; Piedade, M. Fátima M.; Veiros, Luís F.; Jakusch, Tamás; Kiss, Tamás

The Schiff base N,Nprime-ethylenebis(pyridoxylideneiminato) (H2pyr2en, 1) was synthesized by reaction of pyridoxal with ethylenediamine; reduction of H2pyr2en with NaBH4 yielded the reduced Schiff base N,Nprime-ethylenebis(pyridoxylaminato) (H2Rpyr2en, 2); their crystal structures were determined by X-ray diffraction. The totally protonated forms of 1 and 2 correspond to H6L4+, and all protonation constants wer...

Date: 2004   |   Origin: Estudo Geral - Universidade de Coimbra
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