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Profiting from light-induced metal-to-metal intramolecular electron transfer

Sanz-Villafruela, Juan; Servos, Lisa Marie; Montesdeoca, Nicolás; Cuevas-Vicario, José V.; Moro, Artur J.; Lima, João C.; Martínez-Alonso, Marta

Funding Information: J. K. gratefully acknowledges the financial support provided by the Liebig fellowship from the Chemical Industry Fund of the German Chemical Industry Association, the Life Sciences Bridge Award from the Aventis Foundation, and the Paul Ehrlich & Ludwig Darmstaedter Early Career Award 2024 \u2013 a prize awarded by the Paul Ehrlich Foundation, Germany. G. E. acknowledges the financial suppor...


Ir(III) Half-Sandwich Photosensitizers with a π-Expansive Ligand for Efficient ...

Gonzalo-Navarro, Carlos; Zafon, Elisenda; Organero, Juan Angel; Jalón, Félix A.; Lima, João Carlos; Espino, Gustavo; Rodríguez, Ana María; Santos, Lucía

This work was supported by the Spanish Ministerio de Ciencia, Innovación y Universidades (PID2021-127187OB-C21, PID2021-127187OB-C22), PID2019-105408GB-I00, Junta de Comunidades de Castilla-La Mancha-FEDER (JCCM) (grant SBPLY/19/180501/000260), Junta de Castilla y León (BU087G19), and UCLM-FEDER (grants 2019-GRIN-27183 and 2019-GRIN-27209). C.G. acknowledges his fellowship to both the European Social Fund and P...


Towards efficient Ir(iii) anticancer photodynamic therapy agents by extending π...

Sanz-Villafruela, Juan; Bermejo-Casadesús, Cristina; Martínez-Alonso, Marta; Moro, Artur; Lima, João C.; Massaguer, Anna; Espino, Gustavo

Funding Information: This work was supported by the MCIN/AEI of Spain (projects PID2021-127187OB-C21 and PID2021-127187OB-C22). The PhD students acknowledge their predoctoral grants to Universidad de Burgos (J. S. V., 2019/00002/008/001) and University of Girona (C. B., IFUdG 2021). Publisher Copyright: © 2024 The Royal Society of Chemistry.; In this work we disclose a new family of biscyclometallated Ir(iii) c...


Non-emissive RuII Polypyridyl Complexes as Efficient and Selective Photosensiti...

Yagüe, Cristina; Echevarría, Igor; Vaquero, Mónica; Fidalgo, Jairo; Carbayo, Arancha; Jalón, Félix A.; Lima, João C.; Moro, Artur J.; Manzano, Blanca R.

RTI2018-100709-B-C21 CTQ (QMC)-RED2018-102471-T) Junta de Castilla y Leon (BU087G19 FEDER (BU042U16-BU305P18).; Five new RuII polypyridyl complexes bearing N-(arylsulfonyl)-8-amidoquinolate ligands and three of their biscyclometalated IrIII congeners have been prepared and employed as photocatalysts (PCs) in the photooxidation of benzylamines with O2. In particular, the new RuII complexes do not exhibit photolu...


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