The mechanical behavior of agglomerated cork, made of cork granules bound with polyurethane moisture-cured adhesive is investigated and compared to natural cork in the small strain regime (strain < 5%). Dynamic mechanical analysis (DMA) of the agglomerated material revealed two distinct thermal transitions, one at -45 A degrees C, related to the glass transition of polyurethane, and one at 3 A degrees C, associ...
Microcapsules produced by interfacial polycondensation of p-phenylenediamine (PPD) and sebacoyl chloride (SC) were studied. The products were characterized in terms of morphology, mean diameter and effectiveness of dodecane encapsulation. The use of Tween 20 as dispersion stabilizer, in comparison with polyvinyl alcohol (PVA), reduced considerably the mean diameter of the microcapsules and originated smoother w...
Biodegradable polymers can be applied to produce automobile parts, following ecological recommendations and eco-design philosophies. In some applications, a constant or dynamic load applied to the part can further reduce its life cycle due to creep or fatigue cumulative damage. Hence, the reinforcement of these polymers with graphene may enhance the mechanical properties and change the time-dependent mechanical...
In this paper, the use of Automated Bonding Evaluation System (ABES) for evaluation of bonding strength of wood adhesives is presented. A simple reactive model is proposed, which considers the phenomena involved during resin cure: formation of wood-resin-wood bonds. In the present study, experimental data of a standard urea-formaldehyde (UF) resin using different catalysts, phosphoric acid and ammonium sulphate...
In this work, TiO2 nanoparticles were dispersed and stabilized in water using a novel type of dispersant based on tailor-made amphiphilic block copolymers of poly(ethylene glycol)-block-poly(4-vinyl pyridine) (mPEG-b-P4VP) prepared by atom transfer radical polymerization (ATRP). The performance of this new block copolymer as dispersant was compared to a polyelectrolyte dispersant commonly used for TiO2, sodium ...