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Structural and Optical Characterization of Mechanochemically Synthesized CuSbS2...

Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Silva, Teresa; Correia, J.B.; Neves, Filipe

ABSTRACT: The present work describes experimental studies related to the characterization of CuSbS2 directly synthesized after 2 h of mechanochemical synthesis (MCS) at 340 rpm, starting from mixtures of elemental powders. X-ray diffraction (XRD) and UV-VIS-NIR spectroscopy were carried out to analyze the crystal structure, degree of crystallinity, crystallite size and optical properties of the mechanochemicall...

Date: 2022   |   Origin: Repositório do LNEG

Structural and optical characterization of mechanochemically synthesized CuSbS2...

Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Silva, Teresa; Correia, J.B.; Neves, Filipe

ABSTRACT: One of the areas of research on materials for thin-film solar cells focuses on replacing In and Ga with more earth-abundant elements. In that respect, chalcostibite (CuSbS2) is being considered as a promising environmentally friendly and cost-effective photovoltaic absorber material. In the present work, single CuSbS2 phase was synthesized directly by a short-duration (2 h) mechanochemical-synthesis s...

Date: 2022   |   Origin: Repositório do LNEG

Structural and Optical Characterization of Mechanochemically Synthesized CuSbS2...

Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Silva, Teresa; Correia, J.B.; Neves, Filipe

ABSTRACT: The present work describes experimental studies related to the characterization of CuSbS2 directly synthesized after 2 h of mechanochemical synthesis (MCS) at 340 rpm, starting from mixtures of elemental powders. X-ray diffraction (XRD) and UV-VIS-NIR spectroscopy were carried out to analyze the crystal structure, degree of crystallinity, crystallite size and optical properties of the mechanochemicall...

Date: 2022   |   Origin: Repositório do LNEG

Structural and optical characterization of mechanochemically synthesized CuSbS2...

Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Silva, Teresa; Correia, J.B.; Neves, Filipe

ABSTRACT: One of the areas of research on materials for thin-film solar cells focuses on replacing In and Ga with more earth-abundant elements. In that respect, chalcostibite (CuSbS2) is being considered as a promising environmentally friendly and cost-effective photovoltaic absorber material. In the present work, single CuSbS2 phase was synthesized directly by a short-duration (2 h) mechanochemical-synthesis s...

Date: 2022   |   Origin: Repositório do LNEG

LocalEnergy: Local Resources for Multifunctional Tetrahedrite-based Energy: Har...

Neves, Filipe; Correia, J.B.; Esperto, Luís; Mascarenhas, João; Figueira, Isabel; de Oliveira, Daniel Pipa Soares; Salgueiro, Rute; Silva, Teresa

Date: 2022   |   Origin: Repositório do LNEG

Dynamic corrosion testing of metals in solar salt for concentrated solar power

Sutter, Florian; Oskay, Ceyhun; Galetz, Mathias Christian; Cunha Diamantino, Teresa; Pedrosa, Fátima; Figueira, Isabel; Glumm, Stefan; Bonk, Alexander

ABSTRACT: Potassium nitrate and sodium nitrate in mixing proportion of KNO3-NaNO3 40-60 wt% (also called solar salt) has been successfully used for over a decade as heat storage medium for concentrated solar power parabolic-trough collector plants at temperatures up to 400 degrees C. At temperatures of 560 degrees C, reached in state-of-the-art solar tower systems, corrosion of metallic components in contact wi...

Date: 2021   |   Origin: Repositório do LNEG

Recovery of mining waste as source of raw material for the synthesis of tetrahe...

Neves, Filipe; Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Salgueiro, Rute; Silva, Teresa; Correia, J.B.; Carvalho, Patricia Almeida

Date: 2021   |   Origin: Repositório do LNEG

Dynamic corrosion testing of metals in solar salt for concentrated solar power

Sutter, Florian; Oskay, Ceyhun; Galetz, Mathias Christian; Cunha Diamantino, Teresa; Pedrosa, Fátima; Figueira, Isabel; Glumm, Stefan; Bonk, Alexander

ABSTRACT: Potassium nitrate and sodium nitrate in mixing proportion of KNO3-NaNO3 40-60 wt% (also called solar salt) has been successfully used for over a decade as heat storage medium for concentrated solar power parabolic-trough collector plants at temperatures up to 400 degrees C. At temperatures of 560 degrees C, reached in state-of-the-art solar tower systems, corrosion of metallic components in contact wi...

Date: 2021   |   Origin: Repositório do LNEG

Mechanochemical synthesis of tetrahedrite materials using mixtures of synthetic...

Neves, Filipe; Esperto, Luís; Figueira, Isabel; Mascarenhas, João; Salgueiro, Rute; Silva, Teresa; Correia, J.B.; Carvalho, Patricia Almeida

ABSTRACT: Considering that the synthesis of tetrahedrite-based materials usually uses high purity elements, the evaluation of the direct application of ore samples as raw materials for their synthesis is a pertinent issue. In the present study, multiphase synthetic tetrahedrite samples were mixed with tetrahedrite-tennantite ore samples (in weight ratios of 0.8/0.2, 0.5/0.5 and 0.2/0.8) to produce tetrahedrite-...

Date: 2021   |   Origin: Repositório do LNEG

Corrosão de aços inoxidáveis austeníticos em sais fundidos ternários de cálcio

Cunha Diamantino, Teresa; Gomes, A.; Paiva Luís, Teresa; Figueira, Isabel; Pedrosa, Fátima; Nogueira, Carlos; Guerreiro, L.; Collares-Pereira, M.

RESUMO: O armazenamento de energia térmica (TES) é um fator chave para melhorar a eficiência e a despachabilidade dos diferentes sistemas energéticos, devido a um melhor ajustamento entre a procura e a oferta de energia, e ao permitir o desenvolvimento e a implementação de energias renováveis. Um exemplo claro é o TES em instalações de concentração de energia solar (CSP), onde o excesso de energia solar durante...

Date: 2020   |   Origin: Repositório do LNEG

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