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Electrochemical Applications of Metal-Organic Frameworks: Overview, Challenges,...
Boldrin, Maria Valnice [UNESP]; Irikura, Kallyni [UNESP]; Costa E Silva, Beatriz [UNESP]; Cardoso, Juliano Carvalho; Stulp, SimoneMade available in DSpace on 2022-04-28T19:47:19Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-01-01; Applications for Biomass Conversion and CO2Capture. Metal-organic frameworks (MOFs) have emerged as highly customizable catalysts based on their unique features. Recent studies have developed specific MOFs for many applications. As part of a three-volume set (1393-1395), this volume provides an overview...
Electrochemical preparation of Cu/Cu2O-Cu(BDC) metal-organic framework electrod...
Silva, Beatriz Costa E [UNESP]; Irikura, Kallyni [UNESP]; Flor, Jader Barbosa Silva [UNESP]; Dos Santos, Rodrigo Morais Menezes [UNESP]Made available in DSpace on 2021-06-25T11:05:29Z (GMT). No. of bitstreams: 0 Previous issue date: 2020-12-01; Thin films of the metal-organic framework (MOF) Cu(BDC) were electrochemically grown by anodic deposition of the ligand 1,4-benzenedicarboxylate (1,4-BDC) on metallic copper to form Cu/Cu2O-Cu(BDC) electrode. The construction of the electrode was optimized by investigating parameters such as current den...
Direct synthesis of Ru3(BTC)2metal-organic framework on a Ti/TiO2NT platform fo...
Irikura, Kallyni [UNESP]; Perini, João Angelo Lima [UNESP]; Flor, Jader Barbosa Silva [UNESP]; Frem, Regina Célia Galvão [UNESP]Made available in DSpace on 2021-06-25T11:08:28Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-01-01; This work describes the use of a thin film of Ru3(BTC)2 metal-organic framework (MOF) deposited onto Ti/TiO2 nanotubes as a photocathode in CO2 reduction. This approach combines the advantages of the ruthenium MOF as a heterogeneous catalyst and as an agent for trapping CO2 on its active sites, resultin...
Effect of Cu(BDC-NH2) MOF deposited on Cu/Cu2O electrode and its better perform...
Silva, Beatriz Costa e [UNESP]; Irikura, Kallyni [UNESP]; Frem, Regina Célia Galvão [UNESP]; Zanoni, Maria Valnice Boldrin [UNESP]Made available in DSpace on 2021-06-25T11:09:37Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-01-01; Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq); Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP); The present work reports the development of Cu/Cu2O-Cu(BDC-NH2) electrode, prepared by electrochemical deposition using the ligand 2-amino-1,4-benzenedicarboxylic acid and...
Ru-90@bio-MOF-1: A ruthenium(II) metallodrug occluded in porous Zn-based MOF as...
Marson Armando, Renan Augusto [UNESP]; Abuçafy, Marina Paiva [UNESP]; Graminha, Angelica Ellen; Silva, Roberto Santana daMade available in DSpace on 2021-06-25T10:24:57Z (GMT). No. of bitstreams: 0 Previous issue date: 2021-05-01; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES); Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq); Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP); One of the major challenges in the field of biomedicine is to use biocompatible carriers to achieve ef...
Chemical transformation of a luminescent two-dimensional Eu(iii) coordination p...
Da Silva, Caroline Moraes [UNESP]; Ellena, Javier; Frem, Regina Célia Galvão [UNESP]Made available in DSpace on 2020-12-12T01:30:08Z (GMT). No. of bitstreams: 0 Previous issue date: 2020-06-28; In this work, the 2D Eu(iii) coordination polymer {[Eu(HPDC)(PDC)]}n (PDC = 2,6-pyridinedicarboxylate) (1) was prepared in a fast manner via microwave-assisted hydrothermal synthesis. The same compound was obtained by a conventional hydrothermal route and had its structure determined through single crys...
Synthesis of whey peptide-iron complexes: Influence of using different iron pre...
Caetano-Silva, Maria Elisa; Alves, Renata Carolina [UNESP]; Lucena, Guilherme Nunes [UNESP]; Frem, Regina Célia Galvão [UNESP]Made available in DSpace on 2018-12-11T16:49:14Z (GMT). No. of bitstreams: 0 Previous issue date: 2017-11-01; Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP); Iron-binding peptides are an alternative for increasing the bioavailability of iron and to decreasing its pro-oxidant effect. This study aimed to synthesize and characterize peptide-iron complexes using FeCl2 or FeSO4 as the iron precursor c...
A new luminescent silver-based probe for on/off sulfide determination
Segura, Daniel Fonseca [UNESP]; Petruci, João Flávio Da Silveira [UNESP]; Cardoso, Arnaldo Alves [UNESP]; Frem, Regina Célia Galvão [UNESP]Made available in DSpace on 2018-12-11T16:59:30Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-01-01; The sulfide anion is a corrosive, toxic and harmful compound found in a wide range of anoxic environments. Metal-based complexes have been used as luminescent probes for sulfide determination. However, their synthesis usually involves laborious procedures and the use of toxic reagents. In this paper, we...
Nitrite Reduction Enhancement on Semiconducting Electrode Decorated with Copper...
Sayão, Fabiana A. [UNESP]; da Silva Flor, Jader Barbosa [UNESP]; Frem, Regina Célia Galvão [UNESP]; Stulp, Simone; Cardoso, Juliano C. [UNESP]Made available in DSpace on 2018-12-11T17:29:50Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-11-01; The present work seeks to describe a new approach characterized by copper(II) aspirinate complex deposited onto nanotube TiO2 electrodes as mediator of electron transfer during nitrite reduction, aiming at achieving a faster removal of nitrite to nitrogen species oxides. Thin films of copper aspirinate ...
An Artificial Photosynthesis System Based on Ti/TiO2 Coated with Cu(II) Aspirin...
Stülp, Simone; Cardoso, Juliano C. [UNESP]; de Brito, Juliana Ferreira [UNESP]; Flor, Jader Barbosa S. [UNESP]; Frem, Regina Célia Galvão [UNESP]Made available in DSpace on 2018-12-11T17:32:04Z (GMT). No. of bitstreams: 0 Previous issue date: 2017-05-01; Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq); Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP); A novel copper(II) aspirinate complex easily deposited onto nanotubes of Ti/TiO2 was successfully employed in the conversion of CO2 to methanol through the use of UV-Vis i...