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Heptacopper(II) and dicopper(II)-adenine complexes: synthesis, structural chara...

Leite Ferreira, B. J. M.; Brandao, Paula; dos Santos, A. M.; Gai, Z.; Cruz, C.; Reis, M. S.; Santos, T. M.; Felix, V.

The syntheses, crystal structures, and magnetic properties of two new copper(II) complexes with molecular formulas [Cu-7((2)-OH2)(6)((3)-O)(6)(adenine)(6)](NO3)(2)6H(2)O (1) and [Cu-2((2)-H2O)(2)(adenine)(2)(H2O)(4)](NO3)(4)2H(2)O (2) are reported. The heptanuclear compound is composed of a central octahedral CuO6 core sharing edges with six adjacent copper octahedra. In 2, the copper octahedra shares one equat...


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