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Reactive nitrogen/oxygen species production by nitro/nitrosyl supramolecular ru...

Barbosa, Marília Imaculada Frazão; Gimenez Parra, Gustavo; Correa, Rodrigo de Souza; Sampaio, Renato Neiva; Magno, Lais Nogueira; Silva, Rodrigo Costa

This manuscript reports on new nitro/nitrosyl Ru-based complexes, which were synthesized with the purpose of using them as precursors to obtain supramolecular ruthenium porphyrin species ({TPyP[Ru (NO2)(5,50-Mebipy)2]4}(PF6)4) and ({TPyP[Ru(NO)(5,50-Mebipy)2]4}(PF6)12). The photochemical and photophysical properties of these porphyrin species were investigated. Results show that the complex containing nitrite i...

Date: 2018   |   Origin: Oasisbr
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