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Optimization of Heterogeneous Photosensitized Oxidation for Winery Effluent Tre...

Silva, Mariana; Oliveira-Inocêncio, Inês; Martins, Rui C.; Quinta-Ferreira, Rosa M.; Gmurek, Marta; Nogueira, Anabela Gonçalves; Castro-Silva, Sérgio

In this study, the heterogeneous photosensitized oxidation treatment of winery effluents was optimized using chitosan carriers immobilized with Zn(II) Phthalocyanine tetrasulfonic acid. The influence of main operating parameters such as initial pH, aeration flow rate, photocatalyst load, and concentration of the photosensitizer used in the photocatalysts’ preparation was investigated. Results for chemical oxyge...


Homogeneous Photosensitized Oxidation for Water Reuse in Cellars: A Study of Di...

Santos, Andreia D.; Gonçalves, Diana; Martins, Rui C.; Gmurek, Marta; Nogueira, Anabela Gonçalves; Castro-Silva, Sérgio; Castro, Luís M. M. N.

The demand for fresh water is increasing daily, requiring industries to take action to reduce the need for fresh water. Winemaking industries represent a massive hydric impact by combining the water consumed and the high volume of wastewater produced. The sun-driven photooxidation process has been widely employed in removing wastewater pollutants. This work employed four photosensitizers, Rose Bengal, AlPcS4, Z...


Editorial Catalysts: Special Issue on Recent Advances in TiO2 Photocatalysts

Malankowska, Anna; Borowska, Ewa; Martins, Rui C.; Gmurek, Marta


Editorial: Advanced Processes for Wastewater Treatment and Water Reuse

Martins, Rui C.; Ferreira, Rosa M. Quinta; Rasteiro, Maria Graça; Dantas, Renato; Gmurek, Marta


Advanced oxidation processes for recalcitrant compounds removal comparison with...

Gomes, João; Domingues, Eva; Gmurek, Marta; Quinta-Ferreira, Rosa M.; Martins, Rui C.

Conventional treatments cannot remove the emerging contaminants due to their refractory character, therefore improved methodologies should be applied for obtaining their total removal. The need of development of suitable technologies to treat these recalcitrant compounds is related with the wastewater reclamation. Advanced oxidation technologies such as photocatalysis and ozonation appear as suitable solutions ...


Ozone and Photocatalytic Processes for Pathogens Removal from Water: A Review

Gomes, João; Matos, Ana M.; Gmurek, Marta; Quinta-Ferreira, R. M.; Martins, Rui C.

The search for alternative water sources is pushing to the reuse of treated water coming from municipal wastewater treatment plants. However, this requires that tightened standards be fulfilled. Among them is the microbiological safety of reused water. Although chlorination is the mostly applied disinfection system, it presents several disadvantages, such as the high doses required and the possibility of format...


Solar Photocatalytic Degradation of Sulfamethoxazole by TiO2 Modified with Nobl...

Borowska, Ewa; Gomes, João; Martins, Rui C.; Quinta-Ferreira, R. M.; Horn, Harald; Gmurek, Marta

Application of solar photocatalysis for water treatment is intensively studied. In this work, we investigated TiO2 modified with platinum (Pt/TiO2) and palladium (Pd/TiO2) using sulfamethoxazole (SMX) as the model contaminant. We considered the following parameters: (i) level of TiO2 modification with Pt/Pd, (ii) initial concentration of photocatalysts, (iii) geographic location where processes were conducted, ...


Effect of Different Radiation Sources and Noble Metal Doped onto TiO2 for Conta...

Martins, Rui C.; Domingues, Eva; Bosio, Morgana; Quina, Margarida J.; Gmurek, Marta; Quinta-Ferreira, Rosa M.; Gomes, João

Water scarcity is a worldwide problem boosted by global warming and pollution of anthropogenic origin. The contaminants of emerging concern in water sources are increasing due to the ine ciency of conventional wastewater treatments, and these should be mitigated. Advanced oxidation processes appear as suitable solutions for decontamination. The photocatalytic oxidation of the mixture of sulfamethoxazole, carbam...


Effect of Noble Metals (Ag, Pd, Pt) Loading over the Efficiency of TiO2 during ...

Gomes, João F.; Lopes, Ana; Bednarczyk, Katarzyna; Gmurek, Marta; Stelmachowski, Marek; Zaleska-Medynska, Adriana; Quinta-Ferreira, M. Emilia

The conventional wastewater treatments are inadequate for emerging contaminants detoxification. Photocatalytic ozonation with suitable catalyst can be considered as a suitable solution on the removal of these compounds. The aim of this study was to verify the effect of Ag, Pd and Pt with different loadings (0.1, 0.5 and 1% wt %) onto TiO2 surface for the degradation of a mixture of parabens (methyl, ethyl, prop...


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