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A structure-based catalytic mechanism for the xanthine oxidase family of molybd...
Huber, Robert; Hof, Peter; Duarte, Rui O.; Moura, Jose J. G.; Moura, Isabel; Liu, Ming Yih; LeGall, Jean; Hille, Russ; Archer, MargaridaThe crystal structure of the xanthine oxidase-related molybdenum-iron protein aldehyde oxidoreductase from the sulfate reducing anaerobic Gram- negative bacterium Desulfovibrio gigas (Mop) was analyzed in its desulfo-, sulfo-, oxidized, reduced, and alcohol-bound forms at 1.8-Å resolution. In the sulfo-form the molybdenum molybdopterin cytosine dinucleotide cofactor has a dithiolenebound fac-[Mo, =O, =S, ···(OH...
Date: 1996
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Origin: Repositório Institucional da UNL