Titanate nanotubes (TiNTs) with the chemical composition Na2Ti3O7.nH2O (NaTiNT) were obtained through a hydrothermal method in highly alkaline medium. Protonated titanates nanotubes (H-TiNTs), with the composition H2Ti3O7.nH2O, were prepared by ion exchange reaction through a suspension of Na2Ti3O7nH2O nanotubes in HCl medium, promoting the exchange of Na+ ions by H+. Both Na2Ti3O7.nH2O and H2Ti3O7.nH2O produc...
A Lipase de Thermomyces lanuginosus (TLL) foi imobilizada em nanopartículas superparamagnéticas (NMP) de ferro (Fe3O4) visando a fácil recuperação do biocatalisador, por exemplo, pela aplicação de um campo magnético. Para se avaliar a influência da superfície do suporte na atividade do catalisador, as NPM foram modificadas pelo recobrimento com γ-aminopropiltrietoxissilano (APTES) ou com polietilenimina ramific...
A Lipase de Thermomyces lanuginosus (TLL) foi imobilizada em nanopartículas superparamagnéticas (NPM) de ferro (Fe3O4) para melhorar a estabilidade deste biocatalisador e facilitar a recuperação do mesmo por aplicação de campo magnético. As NPM utilizadas apresentam modificações em suas superfícies dadas pelo recobrimento com γ-aminopropiltrietoxissilano (APTES) ou com polietilenimina ramificada (BPEI), o que m...
Com o desenvolvimento da tecnologia sem fio, muitos dispositivos eletrônicos exigem alta integração e que possuam propriedades multifuncionais. Em tal caso, compósitos magneto-dielétricos têm atraído muita atenção, porque eles têm tanto propriedades dielétricas como magnéticas. O titanato de cálcio e a granada de ítrio e ferro possuem excelentes propriedades dielétricas e ferrimagnéticas, respectivamente. O obj...
O presente trabalho teve como objetivo investigar a adsorção de imunoglobulina G (IgG) em corante reativo vermelho - Procion Red MX-5B (PR) – imobilizado em microesferas compósitas quitosana/alginato. Foram realizados ensaios em batelada com o adsorvente a fim de obter o efeito do pH, o tempo de contato e a isoterma de adsorção com a proteína IgG. O tempo necessário para estabelecer o equilíbrio foi de 4 horas ...
In this study, lipase from Pseudomonas fluorescens was immobilized on octyl-nanoparticles by hydrophobic interaction, producing the biocatalyst OCTYL-NANO-PSF. In order to stabilize the immobilized enzyme on OCTYL-NANO, an additional step was conducted, which is the reticulation with different concentrations of glutaraldehyde (GA), producing OCTYL-NANO-PSF-GA preparations. The concentrations of glutaraldehyde w...
This work reports the dielectric properties of Sr3WO6 (SWO) double perovskite at radio frequencies as a function of the temperature and a study in microwaves range to evaluate the material as a novel dielectric resonator. Thermo-activated charge transfer process for SWO ceramic was observed and two resistor–capacitor associations were fitted for the Nyquist diagram. SWO presented negative values of temperature ...
Made available in DSpace on 2018-12-11T16:42:30Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-01-01. Added 1 bitstream(s) on 2019-10-09T18:28:39Z : No. of bitstreams: 1 S0104-14282016000100004.pdf: 2694467 bytes, checksum: 0929ba44ac932c2a7b7aa1ba5273d042 (MD5); A growing global trend for maximum use of natural resources through new processes and products has enhanced studies and exploration of renewab...
Due to a fast progress in the development of communication systems, the dielectric and magnetic ceramics (ferrites) have become attractive to be used in devices. Although the ferrites of the spinel type were the first material used in the microwave range, garnets have smaller dielectric losses and, therefore, are chosen for many applications. High demands for modern electric applications in magnetic materials r...
We report Raman scattering and x-ray diffraction studies of polycrystalline CaCu3Ti4O12 (CCTO) under high pressures. The pressure dependence of several Raman modes was investigated. No anomalies have been observed on the phonon spectra thereby indicating that the Th sIm 3¯d structure remains stable up to the maximum pressure s5.3 GPad we reached in this experiment. The pressure coefficients for the observed Ram...