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Ion binding to natural organic matter: General considerations and the NICA-Donn...

Koopal, L. K.; Saito, T.; Pinheiro, J. P.; Van Riemsdijk, W. H.

The general principles of cation binding to humic matter and the various aspects of modeling used in general-purpose speciation programs are discussed. The discussion will focus on (1) the discrimination between chemical and electrostatic interactions, (2) the binding site heterogeneity, (3) the models for the electrostatic interactions, such as the Donnan model and (4) the complications inherent to ion binding...


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