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Picosecond Structural Relaxation of Abietic Acid Based Amine End Capped Para-Ph...

Paolo, Roberto E. Di; Gigante, Barbara; Esteves, Maria A.; Pires, Natércia; Santos, Célia; Lameiro, Maria H.; Melo, João Seixas de; Burrows, Hugh D.

The synthesis and photophysical properties of six new abietic acid based amine end-capped p-phenylenevinylene trimers (AECPV3) in their lowest excited singlet states are presented. The AECPV3 compounds show a large red-shift of both the absorption (25-30 nm) and emission (37-42 nm) maxima with respect to those of the corresponding trimers. Picosecond time-resolved fluorescence data reveal the presence of a fast...


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