Optical biosensors based on localized surface plasmon resonance (LSPR) are the future of label-free detection methods. This work reports the development of plasmonic thin films, containing Au nanoparticles dispersed in a TiO2 matrix, as platforms for LSPR biosensors. Post-deposition treatments were employed, namely annealing at 400 °C, to develop an LSPR band, and Ar plasma, to improve the sensitivity of the Au...
Optical biosensors based on localized surface plasmon resonance (LSPR) are the future of label-free detection methods. This work reports the development of plasmonic thin films, containing Au nanoparticles dispersed in a TiO<sub>2</sub> matrix, as platforms for LSPR biosensors. Post-deposition treatments were employed, namely annealing at 400 °C, to develop an LSPR band, and Ar plasma, to improve the sensitivit...
The photophysical properties of iridium(III) porphyrins complexes with two different axial ligands (Cl(CO) and bipyridine (bpy)) in solution and in cellulose acetate polymer matrix were investigated. The axial ligands substitution was made aiming to evaluate the photophysical properties and the solubility in different solvents. Therefore, dissimilar from the free porphyrin, non-polar solvents (as toluene) favou...
Battery separator membranes for lithium-ion batteries have been developed based on poly(vinylidene fluoride), PVDF, and using the “green solvent” - N,N’-dimethylpropyleneurea (DMPU). This separator presents a porous microstructure with a degree of porosity of 20% and pore size below 1 µm, showing excellent mechanical properties. Further, its ionic conductivity, tortuosity and MacMullin number values are 0.1 mS....
The role of temperature, shear and oxygen on PLA degradation was investigated. Thermo-mechanical degradation induces a larger decrease in PLA molecular weight than thermo-oxidative degradation. This was associated with different degradation processes (mainly chain scission) that took place under the two conditions. Given the PLA robustness to endure reprocessing, it was possible to conclude that the primary and...
Recent Advances in Antioxidant Active Food Packaging: Food oxidation; Antioxidants; Food Packaging; Active Packaging; Legislation; Natural antioxidants.
Natural antioxidants applied in Active food Packaging: Food oxidation; Antioxidants; Food Packaging; Active Packaging; Legislation; Natural antioxidants.
Aromatic plants have been used in cooking and in folk medicine for centuries. However, in the last few years aromatic plants have received particular attention due to their simple and efficient contribution to decrease salt daily intake. The present study evaluated the two biologically active forms of vitamin C, L-ascorbic acid and dehydroascorbic acid, by high performance liquid chromatography coupled with dio...
Recent Advances in Antioxidant Active Food Packaging: Food oxidation; Antioxidants; Food Packaging; Active Packaging; Legislation; Natural antioxidants.
Introduction: Aromatic herbs have been used over the centuries, ubiquitously, with culinary or medicinal purposes. Nowadays they attract the interest of the scientific community due to their potential health benefits namely regarding oxidative processes in the body, such as age-related degenerative disorders and metabolic diseases, because herbs are considered a source of antioxidants. The use of antioxidants i...