ABSTRACT: Due to their remarkable characteristics, cellulose nanocrystals are strategic materials that has various industrial applications, and are capable of being produced from vegetable fibers derived from the discards of agricultural practices. Peanut(Arachis hypogaea L.) peel is a residue considered of low commercial value and high polluting potential that needs new applications in order to mitigate these ...
Biomaterials have been intensively investigated due to the increase in the elderly population and high prevalence of several disorders, such as cardiovascular and orthopedic diseases. Polymeric and composite polymeric materials in combination with different processing techniques, such as electrospinning, solution blow spinning, ultrathin film preparation, and 3D printing are promising for obtaining biomaterials...
Abstract Blends of zein and poly(vinyl alcohol) (PVAl) were processed in an internal mixer (150ºC, 50 rpm) for 5-8 minutes. Glycerol and oleic acid were used as plasticizers. The mixtures obtained were then compression molded and further characterized by Fourier transform infrared spectroscopy (FTIR), water-absorption experiments, mechanical tests, and scanning electron microscopy (SEM). FTIR analysis indicated...
Abstract The non-isothermal decomposition kinetics of conductive polyaniline (PANI) and its derivatives, poly(o-methoxyaniline) (POMA) and poly(o-ethoxyaniline) (POEA), was investigated by thermogravimetric analysis (TGA), under inert and oxidative atmospheres, using Flynn-Wall-Ozawa’s approach to assess the kinetic parameters of the decomposition process. The order of reaction was found to be dependent on the ...
Thermoplastic starch properties depends of plastification process. The aim of this study was to analyze the effect of concentration of glycerol and water on plastification, glass transition temperature (Tg) and tensile properties of thermoplastic waxy starch (TPWS). Formulations were extruded in the following concentrations of starch/glycerol/water: 70/30/0 (TPWS 0%); 70/25/5 (TPWS 5%); 70/20/10 (TPWS 10%) weig...
RESUMO O isolamento de nanocristais de celulose (CNCs) de fibras vegetais é uma alternativa promissora para sua aplicação como reforço em matrizes poliméricas. A caracterização dos CNCs é fundamental para a confiabilidade da técnica, além de determinar as aplicações possíveis a partir de cada tipo de fibra. A partir da técnica de microscopia de força atômica, um estudo da morfologia e distribuição dos CNCs de s...
Abstract This paper reports on a study of highly filled composites of polypropylene (PP) and 75% by weight sugarcane bagasse fiber with and without alkali treatment and with and without coupling agent (SEBS-g-MA). Composites were prepared using a Rheomix600 mixer connected to a HAAKE torque rheometer. The thermal and mechanical behavior of these composites were investigated by thermogravimetry (TGA), differenti...
Resumo Este trabalho propõe um novo método de produção de filmes estáveis para aplicações em sensores baseado na deposição pela técnica de automontagem de poli(o-etoxianilina) alternada com fenol-formaldeído (POEA/PF) seguida por cura térmica. O processo de reticulação foi caracterizado por espectroscopias no infravermelho por transformada de Fourier e no ultravioleta-visível, microscopia de força atômica e est...
Neste trabalho, o objetivo foi produzir nanobiocompósitos biodegradáveis à base de pectina e nanoemulsão de canela que tenham propriedades satisfatórias para aplicação como embalagens ativas. Foram detalhados os procedimentos de preparação das nanoemulsões e incorporação dessas na matriz polimérica. Foi apresentada uma metodologia nova de análises dos melhores nanocompósitos através de um planejamento baseado e...
In this study, the effect of rootstock on grafting through metabolomic analysis of latex (Hevea brasiliensis) samples was verified by ¹H nuclear magnetic resonance (NMR) and multivariate data analysis. Sixteen metabolites present in the latex cytosol were characterized by NMR. PCA analysis showed that the latex samples of the RR and GR groups can be differentiated. The GR group samples present a metabolic profi...