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Association of a Hydrophobically Modified Polyelectrolyte and a Block Copolymer...

Costa, Telma; Schillén, Karin; Miguel, Maria da G.; Lindman, Björn; Melo, J. Seixas de

By using absorption and fluorescence (steady-state and time-resolved) techniques, the interaction between a poly(acrylic acid) (PAA), randomly grafted with pyrene (Py) units (PAAMePy55), and a triblock copolymer of poly(ethylene oxide) and poly(propylene oxide) (EO20PO68EO20, P123) was investigated. From the fluorescence data, it is shown that upon addition of P123 a decrease of the (pyrene−pyrene, Py−Py) intra...


Complex Formation between a Fluorescently-Labeled Polyelectrolyte and a Tribloc...

Costa, Telma; Melo, J. Seixas de; Miguel, Maria da G.; Lindman, Björn; Schillén, Karin

The association between a randomly pyrene labeled PAA polymer (PAAMePy55) and a PEO−PPO−PEO triblock copolymer (P123) in aqueous solutions of different NaCl concentrations and pHs has been studied by means of dynamic light scattering (DLS) and steady-state fluorescence spectroscopy at 40 °C. At acidic pH values, in the low P123/PAAMePy55 molar ratio regime (i.e., at low P123 concentrations), the relaxation time...


Spontaneous Formation of Vesicles and Dispersed Cubic and Hexagonal Particles i...

Rosa, Mónica; Infante, Maria Rosa; Miguel, Maria da G.; Lindman, Björn

Mixed catanionic surfactant systems based on amino acids were investigated with respect to the formation of liquid crystal dispersions and the stability of the dispersions. The surfactants used were arginine-N-lauroyl amide dihydrochloride (ALA) and Nα-lauroyl-arginine-methyl ester hydrochloride (LAM), which are arginine-based cationic surfactants; sodium hydrogenated tallow glutamate (HS), a glutamic-based ani...


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