A síntese e caracterização de nanotubos de titanatos intercalados com metais de transição (Al3+, Ni2+, Cr2+ e Co2+) foram investigadas. Os sólidos foram caracterizados quanto as suas propriedades físico-químicas por Microscopia eletrônica de varredura acoplada a EDS (MEV-EDS), difração de raios-X (DRX), espectroscopia Raman, isotermas de adsorção-dessorção de nitrogênio. A atividade catalítica dos sólidos na re...
Nanosized FeCo-based solids were prepared via distinct preparation procedures. The catalytic performances of the solids for styrene oxidation in the presence of hydrogen peroxide were evaluated. The addition of promoters in FeCo such as Sn, Mo, or Cu was also investigated. The catalysts were characterized with XRD, Raman spectroscopy, TEM, chemical analyses, EPR and SEM-EDS. Of these solids obtained via four di...
The action of nanosized Pt-containing Al2O3 catalysts to avoid coking and sintering was studied in steam reforming of glycerol. The solids exhibited almost 100% conversion toward syngas produced at a suitable water to glycerol ratio. Depending on the promoter, a drastic drop in hydrogen yield was observed due to coking and sintering effects. Spent catalyst characterizations by Raman, HRTEM, XRD, TG and SEMEDS a...
Porous ternary Fe-based catalysts were characterized and their catalytic properties through the oxidative dehydrogenation of ethylbenzene in the presence (ODH) or absence (DH) of carbon dioxide were investigated. The catalysts were characterized by X-ray diffraction (XRD), chemical analyses, thermoprogrammed reduction (TPR), physisorption measurements, Raman spectroscopy and scanning electron microscopy coupled...
Various porous binary oxides with elevated textural properties were obtained in this work. The as-synthesized solids were calcined or modified by reflux and extraction processes. Characterizations through SEM, nitrogen physisorption and TEM techniques demonstrated the formation of porous metal oxide networks over all solids. XRD, thermal analyses and FTIR measurements showed the existence of nanosized rutile Ti...
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Trabalho completo: acesso restrito, p.11–14; Submitted by Bruna Lessa (lessbruna@gmail.com) on 2012-06-29T17:04:24Z No. of bitstreams: 2 (89)1-s2.0-S1566736709002994-main.pdf: 267868 bytes, checksum: bd0c14db99d6a046d02d8c340732b51b (MD5) (89)1-s2.0-S1566736709002994-main.pdf: 267868 bytes, checksum: bd0c14db99d6a046d02d8c340732b51b (MD5); Made available in DSpace on 2012-06-29T17:04:24Z (GMT). No. of bitstream...
RESTRITO; Submitted by Santiago Fabio (fabio.ssantiago@hotmail.com) on 2012-07-10T15:03:36Z No. of bitstreams: 1 EE.pdf: 55781 bytes, checksum: a5845e6ef63ea7a99bdc53e2d2d2f81f (MD5); Made available in DSpace on 2012-07-10T15:03:36Z (GMT). No. of bitstreams: 1 EE.pdf: 55781 bytes, checksum: a5845e6ef63ea7a99bdc53e2d2d2f81f (MD5) Previous issue date: 2006; Acid and superacid solids were evaluated in n-butane iso...