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Nanotubos de titanatos contendo metais de transição aplicados na condensação de...

Bessa, Bruno dos Santos; Oliveira, Alcineia Conceição; Mendes Filho, Josué; Viana Neto, Bartolomeu Cruz

A síntese e caracterização de nanotubos de titanatos intercalados com metais de transição (Al3+, Ni2+, Cr2+ e Co2+) foram investigadas. Os sólidos foram caracterizados quanto as suas propriedades físico-químicas por Microscopia eletrônica de varredura acoplada a EDS (MEV-EDS), difração de raios-X (DRX), espectroscopia Raman, isotermas de adsorção-dessorção de nitrogênio. A atividade catalítica dos sólidos na re...

Date: 2020   |   Origin: Oasisbr

Styrene oxidation to valuable compounds over nanosized FeCo-based catalysts: ef...

Oliveira, Ana Paula Saraiva; Gomes, Igor Santos; Oliveira, Alcineia Conceição; Mendes Filho, Josué; Saraiva, Gilberto Dantas; Soares, João Maria

Nanosized FeCo-based solids were prepared via distinct preparation procedures. The catalytic performances of the solids for styrene oxidation in the presence of hydrogen peroxide were evaluated. The addition of promoters in FeCo such as Sn, Mo, or Cu was also investigated. The catalysts were characterized with XRD, Raman spectroscopy, TEM, chemical analyses, EPR and SEM-EDS. Of these solids obtained via four di...

Date: 2018   |   Origin: Oasisbr

Nanosized Pt-containing Al2O3 as an efficient catalyst to avoid coking and sint...

Carvalho, Davi Coelho de; Sousa, Helvio Silvester Andrade de; Mendes Filho, Josué; Assaf, Elisabete Moreira; Thyssen, Vivian Vazquez

The action of nanosized Pt-containing Al2O3 catalysts to avoid coking and sintering was studied in steam reforming of glycerol. The solids exhibited almost 100% conversion toward syngas produced at a suitable water to glycerol ratio. Depending on the promoter, a drastic drop in hydrogen yield was observed due to coking and sintering effects. Spent catalyst characterizations by Raman, HRTEM, XRD, TG and SEMEDS a...

Date: 2018   |   Origin: Oasisbr

Porous ternary Fe-based catalysts for the oxidative dehydrogenation of ethylben...

Ferreira, Nuryana Alves; Mendes Filho, Josué; Oliveira, Alcineia Conceição

Porous ternary Fe-based catalysts were characterized and their catalytic properties through the oxidative dehydrogenation of ethylbenzene in the presence (ODH) or absence (DH) of carbon dioxide were investigated. The catalysts were characterized by X-ray diffraction (XRD), chemical analyses, thermoprogrammed reduction (TPR), physisorption measurements, Raman spectroscopy and scanning electron microscopy coupled...

Date: 2018   |   Origin: Oasisbr

Binary oxides with defined hierarchy of pores in the esterification of glycerol

Alves, Nuryana Ferreira; Santiago Neto, Antonio de Brito; Bessa, Bruno dos Santos; Oliveira, Alcemira Conceição; Mendes Filho, Josué

Various porous binary oxides with elevated textural properties were obtained in this work. The as-synthesized solids were calcined or modified by reflux and extraction processes. Characterizations through SEM, nitrogen physisorption and TEM techniques demonstrated the formation of porous metal oxide networks over all solids. XRD, thermal analyses and FTIR measurements showed the existence of nanosized rutile Ti...

Date: 2018   |   Origin: Oasisbr

Studies of catalytic activity and coke deactivation of spinel oxides during eth...

Freire, Rafael M.; Sousa, Francisco F. de; Pinheiro, Anderson L.; Longhinotti, Elisane; Mendes Filho, J.; Oliveira, Alcemira Conceição

Texto completo: acesso restrito. p. 165-179; Submitted by Suelen Reis (suziy.ellen@gmail.com) on 2013-10-11T12:08:24Z No. of bitstreams: 1 1-s2.0-S0926860X09001574-main.pdf: 834366 bytes, checksum: ff710893da1fa4171688240f210f8ac8 (MD5); Approved for entry into archive by Rodrigo Meirelles (rodrigomei@ufba.br) on 2013-11-18T21:18:58Z (GMT) No. of bitstreams: 1 1-s2.0-S0926860X09001574-main.pdf: 834366 bytes, ch...

Date: 2013   |   Origin: Oasisbr

Nanocasted oxides for gas phase glycerol conversion

Lima, Cleanio L.; Vasconcelos, Santiago J. S.; M. Filho, Josué; C. Neto, Bartolomeu; Rocha, Maria da Graça Martins Carneiro da; Bargiela, Pascal

Acesso restrito: Texto completo. p. 50-62.; Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2012-02-08T17:48:31Z No. of bitstreams: 1 C__Documents and Settings_rep...t.default_Cache_3_AF_B1197d01.pdf: 927260 bytes, checksum: cf086a47c06b34775ce376fde91ed939 (MD5); Made available in DSpace on 2012-02-08T17:48:31Z (GMT). No. of bitstreams: 1 C__Documents and Settings_rep...t.default_Cache_3_AF_B1197d...

Date: 2012   |   Origin: Oasisbr

Activity of nanocasted oxides for gas-phase dehydration of glycerol

Vasconcelos, Santiago J. S.; Lima, Cleanio L.; M. Filho, Josué; Oliveira, Alcemira Conceição; Barros, Eduardo B.; Sousa, Francisco F. de

Acesso restrito: Texto completo. p. 656-664.; Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2012-03-02T11:49:52Z No. of bitstreams: 1 __pdn.sciencedirect.com_....0-S1385894711000805-main.pdf: 746952 bytes, checksum: 23a443da38e6c3b9983ab1fef9478224 (MD5); Made available in DSpace on 2012-03-02T11:49:52Z (GMT). No. of bitstreams: 1 __pdn.sciencedirect.com_....0-S1385894711000805-main.pdf: 746952 b...

Date: 2012   |   Origin: Oasisbr

Analysis of coke deposition and study of the structural features of MAl2O4 cata...

Pinheiro, Anderson L.; Pinheiro, Antonio N.; Valentini, Antoninho; Mendes Filho, J.; Sousa, Francisco F. de; Sousa, Jackson R. de

Trabalho completo: acesso restrito, p.11–14; Submitted by Bruna Lessa (lessbruna@gmail.com) on 2012-06-29T17:04:24Z No. of bitstreams: 2 (89)1-s2.0-S1566736709002994-main.pdf: 267868 bytes, checksum: bd0c14db99d6a046d02d8c340732b51b (MD5) (89)1-s2.0-S1566736709002994-main.pdf: 267868 bytes, checksum: bd0c14db99d6a046d02d8c340732b51b (MD5); Made available in DSpace on 2012-06-29T17:04:24Z (GMT). No. of bitstream...

Date: 2012   |   Origin: Oasisbr

Acid and Superacid Solids for the Transformation of n-Butane

Oliveira, Alcineia Conceição; Essayem, Nadine; Tuel, Alain; Clacens, Jean-Marc; Taârit, Younes Ben; Oliveira, Alcineia Conceição; Essayem, Nadine

RESTRITO; Submitted by Santiago Fabio (fabio.ssantiago@hotmail.com) on 2012-07-10T15:03:36Z No. of bitstreams: 1 EE.pdf: 55781 bytes, checksum: a5845e6ef63ea7a99bdc53e2d2d2f81f (MD5); Made available in DSpace on 2012-07-10T15:03:36Z (GMT). No. of bitstreams: 1 EE.pdf: 55781 bytes, checksum: a5845e6ef63ea7a99bdc53e2d2d2f81f (MD5) Previous issue date: 2006; Acid and superacid solids were evaluated in n-butane iso...

Date: 2012   |   Origin: Oasisbr

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