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Road tunnel, roadside, and urban background measurements of aliphatic compounds...

Oliveira, Cesar; Martins, Natercia; Mirante, Fátima; Caseiro, Alexandre; Pio, Casimiro; Matos, Manuel; Silva, Hugo; Oliveira, Cristina; Camões, Filomena

Particulate matter samples were collected in a road tunnel in Lisbon (PM0.5, PM0.5-1, PM1-2.5, and PM2.5-10) and at two urban locations representing roadside and background stations (PM2.5 and PM2.5-10). Samples were analysed for organic and elemental carbon (OC and EC), n-alkanes, n-alkenes, hopanes, some isoprenoid compounds, and steranes. Particulate matter concentrations in the tunnel were 17-31 times highe...


Size-segregated chemical composition of aerosol emissions in an urban road tunn...

Pio, Casimiro; Mirante, Fátima; Oliveira, Cesar; Matos, Manuel; Caseiro, Alexandre; Oliveira, Cristina; Querol, Xavier; Alves, Célia; Martins, Natércia

An atmospheric aerosol study was performed in 2008 inside an urban road tunnel, in Lisbon, Portugal. Using a high volume impactor, the aerosol was collected into four size fractions (PM0.5, PM0.5-1, PM1-2.5 and PM2.5-10) and analysed for particle mass (PM), organic and elemental carbon (OC and EC), polycyclic aromatic hydrocarbons (PAH), soluble inorganic ions and elemental composition. Three main groups of com...


Size-segregated chemical composition of aerosol emissions in an urban road tunn...

Pio, Casimiro; Mirante, Fatima; Oliveira, Cesar; Matos, Manuel; Caseiro, Alexandre; Oliveira, Cristina; Querol, Xavier; Alves, Celia; Martins, Natercia

An atmospheric aerosol study was performed in 2008 inside an urban road tunnel, in Lisbon, Portugal. Using a high volume impactor, the aerosol was collected into four size fractions (PM0.5, PM0.5-1, PM1-2.5 and PM2.5-10) and analysed for particle mass (PM), organic and elemental carbon (OC and EC), polycyclic aromatic hydrocarbons (PAH), soluble inorganic ions and elemental composition. Three main groups of com...


OC/EC ratio observations in Europe: Re-thinking the approach for apportionment ...

Casimiro Pio; Cerqueira, Mario; Harrison, Roy M.; Nunes, Teresa; Mirante, Fátima; Alves, Célia; Oliveira, Cesar; Sanchez de la Campa, Ana

This study explores a large set of OC and EC measurements in PM(10) and PM(2.5) aerosol samples, undertaken with a long term constant analytical methodology, to evaluate the capability of the OC/EC minimum ratio to represent the ratio between the OC and EC aerosol components resulting from fossil fuel combustion (OC(ff)/EC(ff)). The data set covers a wide geographical area in Europe, but with a particular focus...


Size distribution of polycyclic aromatic hydrocarbons in a roadway tunnel in Li...

Oliveira, Cesar; Martins, Natércia; Tavares, João; Pio, Casimiro; Cerqueira, Mário; Matos, Manuel; Silva, Hugo; Oliveira, Cristina; Camões, Filomena

Atmospheric aerosols of four aerodynamic size ranges were collected using high volume cascade impactors in an extremely busy roadway tunnel in Lisbon (Portugal). Dust deposited on the tunnel walls and guardrails was also collected. Average particle mass concentrations in the tunnel atmosphere were more than 30 times higher than in the outside urban background air, revealing its origins almost exclusively from f...


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