Pulsed power technologies demand dielectric capacitors that possess a high energy storage density and efficiency at low applied electric fields/voltages. In this work, we engineered the morphology of lead-free \( 0.85[0.6\text{Ba}(\text{Zr}_{0.2}\text{Ti}_{0.8})\text{O}_3–0.4(\text{Ba}_{0.7}\text{Ca}_{0.3})\text{TiO}_3]–0.15\text{SrTiO}_3 \) (BZCT–STO) epitaxial thin films, fabricated using the pulsed laser dep...
Searching for materials that accurately mimic the optical properties of biological tissues is essential, particularly for transcranial photobiomodulation (PBM) research, where it is necessary to comprehend how light propagates through the head tissues. In this research, we characterised, in the 500-1200 nm range, the transmittance spectra of porcine tissues (skin, muscle, cranium, brain, and cerebellum) and dif...
N,N-dimethyl-4-nitroaniline is a piezoelectric organic superplastic and superelastic charge transfer molecular crystal that crystallizes in an acentric structure. Organic mechanical flexible crystals are of great importance as they stand between soft matter and inorganic crystals. Highly aligned poly-l-lactic acid polymer microfibers with embedded N,N-dimethyl-4-nitroaniline nanocrystals are fabricated using th...
O que têm em comum o caminho da lua no mar e a condução autónoma de veículos? A reflexão difusa da luz em superfícies rugosas e materiais heterogêneos é responsável pela visibilidade de objetos que não conseguiríamos ver de acordo com a lei de Snell. O mesmo fenómeno ótico também está na base do funcionamento de sensores remotos chamados LIDARs (abreviação de Light Detection And Ranging) que surgiram nos anos 6...
The aim of this study was to evaluate the fluorescence of white zirconia immersed in coloring and fluorescence liquids subjected to glass infiltration and aging. Sixty zirconia discs were machined and divided into groups. Ten discs received no treated before sintering (NT group), ten discs were immersed in a coloring liquid (A2 group), and ten discs were immersed in a fluorescent liquid (F group). The other thi...
Three barbiturate squaraine dyes derived from indolenine or benzothiazole, with different barbituric acid derivatives were prepared, characterized and photophysically evaluated by standard spectroscopic methods. As expectable for squaraines, these dyes showed narrow and intense absorption and emission bands in the Vis/NIR region. The interaction of synthesized dyes with bovine and human serum albumins (BSA and ...
Apontamentos disponibilizados aos alunos de Mestrado em Ciências do Ambiente no âmbito da Unidade Curricular Materiais para a Energia - ramo Energia, lecionada no primeiro ano, segundo semestre do seu plano curricular.
Statement of problem. Infiltrated zirconia has promising mechanical properties. However, information about its optical behavior is scarce.Purpose. The purpose of this in vitro study was to evaluate the color and translucency of zirconia submitted to infiltration and aging.Material and methods. Sixty zirconia disks were machined. Ten disks received no treatment (NT group), 10 disks were immersed in a coloring li...
This study evaluated the translucency, contrast ratio and fluorescence of resin nanoceramic and zirconia materials employed for manufacturing of the indirect restorations.
Objective: This review integrates published scientific information about the fluorescence of natural teeth, dental resins and ceramics, and the main methods of analysis and quantification presented in the literature. Overview: Fluorescence is an emission of light (photons) by a substance that has absorbed light of higher energy. In natural teeth, it is more intense in the dentin than in the enamel and presents ...