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Recovery of Nd3+ and Dy3+ from E-Waste Using Adsorbents from Spent Tyre Rubbers...

Nogueira, Miguel; Matos, Inês; Bernardo, Maria; Pinto, Filomena; Fonseca, Isabel Maria; Lapa, Nuno

ABSTRACT: This paper investigates the use of spent tyre rubber as a precursor for synthesising adsorbents to recover rare earth elements. Through pyrolysis and CO2 activation, tyre rubber is converted into porous carbonaceous materials with surface properties suited for rare earth element adsorption. The study also examines the efficiency of leaching rare earth elements from NdFeB magnets using optimised acid l...

Date: 2025   |   Origin: Repositório do LNEG

Opportunities and Constraints of the Adsorption of Rare Earth Elements onto Pyr...

Nogueira, Miguel; Bernardo, Maria; Ventura, Márcia; Matos, Inês; Pinto, Filomena; Lapa, Nuno

ABSTRACT: Rare earth elements (REEs), comprising seventeen metallic elements, including lanthanides, scandium, and yttrium, are indispensable for modern technological industries due to their unique properties. However, their supply is critically risky for the European Union, with 95% of global production concentrated in China, Brazil, Vietnam, Russia, India, and Australia. This mini-review examines the adsorpti...

Date: 2024   |   Origin: Repositório do LNEG

Admissibility Grid to Support the Decision for the Preferential Routing of Port...

Crujeira, Teresa; Trancoso, Maria Ascensão; Eusebio, Ana; Oliveira, Ana Cristina; Passarinho, Paula; Abreu, Mariana; Marques, Isabel Paula

ABSTRACT: A methodology was developed to assess the allocation of different types of endogenous waste biomass to eight technologies for producing electricity, heat, biogas and advanced biofuels. It was based on the identification of key physicochemical parameters for each conversion process and the definition of limit values for each parameter, applied to two different matrices of waste biomass. This enabled th...

Date: 2023   |   Origin: Repositório do LNEG

Congenital chylothorax: A series of eight cases

Jorge Antunes, Joana; Borges, Madalena; Mascarenhas, Andreia; Brito, Sara; Iglesias, Célia; Fernandes, Eduardo; Vieira, Eunice; Pinto, Filomena

Introduction: Congenital chylothorax (CC) is the accumulation of lymph in the pleural space. The aim of this study was to review the cases of CC diagnosed in newborns admitted to a level III neonatal intensive care unit between January 2014 and December 2020. Results: Eight cases of CC were identified, all with prenatal diagnosis. After postnatal confirmation of the diagnosis, supportive care and conservative t...


Valorisation of spent tire rubber as carbon adsorbents for Pb(II) and W(VI) in ...

Bernardo, Maria; Lapa, Nuno; Pinto, Filomena; Nogueira, Miguel; Matos, Inês; Ventura, Márcia; Ferraria, Ana Maria; Rego, Ana Maria Botelho do

ABSTRACT: Spent tire rubber-derived chars and their corresponding H3PO4 and CO2-activated chars were used as adsorbents in the recovery of Pb(II) ion and (W(VI)) oxyanion from synthetic solutions. The developed chars (both raw and activated) were thoroughly characterized to have insight about their textural and surface chemistry properties. H3PO4-activated chars presented lower surface areas than the raw chars ...

Date: 2023   |   Origin: Repositório do LNEG

Admissibility Grid to Support the Decision for the Preferential Routing of Port...

Crujeira, Teresa; Trancoso, Maria Ascensão; Eusebio, Ana; Oliveira, Ana Cristina; Passarinho, Paula; Abreu, Mariana; Marques, Isabel Paula

ABSTRACT: A methodology was developed to assess the allocation of different types of endogenous waste biomass to eight technologies for producing electricity, heat, biogas and advanced biofuels. It was based on the identification of key physicochemical parameters for each conversion process and the definition of limit values for each parameter, applied to two different matrices of waste biomass. This enabled th...

Date: 2023   |   Origin: Repositório do LNEG

Effects of Lignin Gasification Impurities on the Growth and Product Distributio...

Pacheco, Marta; Pinto, Filomena; Brunsvik, Anders; Andre, Rui N.; Marques, Paula; Mata, Ricardo; Ortigueira, Joana; Gírio, Francisco; Moura, Patrícia

ABSTRACT: This work evaluated the effects of condensable syngas impurities on the cell viability and product distribution of Butyribacterium methylotrophicum in syngas fermentation. The condensates were collected during the gasification of two technical lignins derived from wheat straw (WST) and softwood (SW) at different temperatures and in the presence or absence of catalysts. The cleanest syngas with 169 and...

Date: 2023   |   Origin: Repositório do LNEG

Steam reforming of biomass gasification gas for hydrogen production: From therm...

Brito, João; Pinto, Filomena; Ferreira, Alexandre; Soria, M. A.; Madeira, Luís M.

ABSTRACT: Biomass gasification produces syngas composed mainly of hydrogen, carbon monoxide, carbon dioxide, methane, water, and higher hydrocarbons, till C4, mainly ethane. The hydrocarbon content can be upgraded into richer hydrogen streams through the steam reforming reaction. This study assessed the steam reforming process at the thermodynamic equilibrium of five streams, with different compositions, from t...

Date: 2023   |   Origin: Repositório do LNEG

Cr(III) dynamic removal in a fixed-bed column by using a co-gasification char

Dias, Diogo; Bernardo, Maria; Pinto, Filomena; Fonseca, Isabel Maria; Lapa, Nuno

ABSTRACT: A char (GC) obtained from the co-gasification of rice husk and polyethylene was used in a fixed-bed column with continuous flow for Cr(III) removal assays from synthetic and industrial wastewaters. For comparison purposes, a commercial activated carbon (CAC) was also used. The best experimental conditions in the continuous removal assays were the following ones: Cr(III) inflow concentration = 5 mg L-1...

Date: 2021   |   Origin: Repositório do LNEG

Use of Therapeutic Hypothermia in Sudden Unexpected Postnatal Collapse: A Retro...

Brito, Sara; Sampaio, Isabel; Dinis, Alexandra; Proença, Elisa; Vilan, Ana; Soares, Eunice; Pinto, Filomena; Tomé, Teresa; Graça, André M.

Introduction: Sudden and unexpected postnatal collapse is a rare event with potentially dramatic consequences. Intervention approaches are limited, but hypothermia has been considered after postnatal collapse. The aim of this study was to analyse sudden and unexpected postnatal collapse cases that underwent therapeutic hypothermia in the five Portuguese hypothermia centres. Material and methods: In this multice...


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