In this study, a mixed-matrix method was used to prepare PVDF polymeric membranes with different amounts of TiO2 P25 photocatalyst embedded, which were employed in filtration processes in the presence of UV radiation (LED, peak emission at 375 nm) to eliminate two aqueous micropollutants (MPs) used as model compounds (venlafaxine and metoprolol). The obtained membranes were characterized to gain insights into t...
The sensory quality of drinking water, and particularly its taste and odor (T&O) is a key determinant of consumer acceptability, as consumers evaluate water by their senses. Some of the conventional treatment processes to control compounds which impart unpleasant T&O have limitations because of their low efficiency and/or high costs. Therefore, there is a great need to develop an effective process for removing ...
Olive mill wastewaters (OMW) consist of high organic contents and are harmful to aquatic and terrestrial biota. Heterogeneous photocatalysis is a technology that can be operated under mild conditions to remove pollutants in the liquid phase. In the present work, graphitic carbon nitride (g-C3N4, hereafter referred to as GCN) is studied for the first time as a metal-free photocatalyst for OMW treatment. The inte...
The nanoparticles designed for application in cancer treatment should have biocompatibility, colloidal stability and triggered release at tumor sites. Magnetic nanoparticles arise as an interesting option to be used as drug nanocarriers, considering the possibility of driving nanoparticles to the correct delivery site and exploring different triggers to achieve such accomplishment. In this study, nickel ferrite...
Metal-free carbon nitride-based membranes were prepared by embedding bulk or exfoliated graphitic carbon nitride (g-C3N4) photocatalysts in a polyvinylidene fluoride (PVDF) matrix. Supported membranes were also fabricated by immobilising these photocatalysts on a polytetrafluoroethylene (PTFE) substrate. The membranes were tested for venlafaxine (VFX) degradation at a feed concentration of 250 mu g L-1 under co...
The intense industrial development has resulted in several consequences for human and environmental health, including the increased discharge of oily products in water bodies. Oily products are widely used in industry, often bearing an associated high cost. Finding alternatives to treat oily wastewater aiming at recovering oily and water phases is an approach allowing recovery of products of economic interest. ...
The combination of photocatalysis with membrane separation technology allows to mitigate potential membrane fouling while degrading the organic micropollutants in water. This work is focused on the immobilization of a gC3N4 promising photocatalyst, in the form of a g-C3N4-PVDF polymeric membrane, for the elimination of representative pharmaceutical substances from complex water matrices in a continuous flow mod...
Powdered catalysts are commonly used in lab-scale tests for the catalytic reduction of oxoanions in drinking water, but their powder nature limits their application at full scale. In this work, Pd and Pd-Cu catalysts (5% wt.) supported on carbon materials with different structural properties, in powder form, were used to prepare catalytic membranes that were tested in a reactor with flow-through configuration (...
The possibility of using hydrogen peroxide (H2O2) as a chemical oxidizer or as a green liquid fuel to produce electricity has encouraged both the scientific and industrial communities to investigate green technologies aimed at the sustainability of the production process. In particular, the light-induced synthesis of H2O2 from water and oxygen has attracted significant attention using optical semiconductors.An ...