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Functional polylactide via ring-opening copolymerisation with allyl, benzyl and...

Lana, Gwenaelle Elza Nathalie Pound; Rabanel, Jean Michel; Hildgen, Patrice; Mosqueira, Vanessa Carla Furtado

A versatile and simple strategy is presented to synthesize reactive polylactide derivatives and their block copolymers with polyethylene glycol. Commercially available glycidyl ethers with an allyl, benzyl or propargyl functional group were copolymerised with D,L-lactide. Tin(II)-2- ethylhexanoate-catalysis produced polymers with up to 4.6, 5.9 and 2.3 allyl, benzyl or propargyl groups per chain, respectively. ...

Date: 2017   |   Origin: Oasisbr
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