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Chemical interaction mechanism of 10-MDP with zirconia

Nagaoka, Noriyuki; Yoshihara, Kumiko; Feitosa, Victor Pinheiro; Tamada, Yoshiyuki; Irie, Masao; Yoshida, Yasuhiro; Meerbeek, Bart Van; Hayakawa, Satoshi

Currently, the functional monomer 10-methacryloyloxy-decyl-dihydrogen-phosphate (10-MDP) was documented to chemically bond to zirconia ceramics. However, little research has been conducted to unravel the underlying mechanisms. This study aimed to assess the chemical interaction and to demonstrate the mechanisms of coordination between 10-MDP and zirconium oxide using 1 H and 31 P magic angle spinning (MAS) nucl...

Date: 2018   |   Origin: Oasisbr

Micro-Raman vibrational Identification of 10-MDP bond to Zirconia and shear bon...

De-Paula, Diego Martins; Loguercio, Alessandro D.; Reis, Alessandra; Frota, Alessandra Reis,2 Natasha Marques; Melo, Radamés; Yoshihara, Kumiko

So far, there is no report regarding the micro-Raman vibrational fingerprint of the bonds between 10-methacryloyloxy-decyl dihydrogen phosphate (10-MDP) and zirconia ceramics. Thus, the aim of this study was to identify the Raman vibrational peaks related to the bonds of 10-MDP with zirconia, as well as the influence on microshear bond strength. Micro-Raman spectroscopy was employed to assess the vibrational pe...

Date: 2018   |   Origin: Oasisbr

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