Seawater electrolysis (SWE) represents a promising approach to green hydrogen (H2) production but currently faces substantial challenges such as the interference of chlorine chemistry and high energy consumption. In this work, we demonstrate that by replacing the energy-demanding oxygen evolution reaction (OER) with the sulfion oxidation reaction (SOR) and by implementing the concept of bipolar membrane (BPM) e...
This work was supported in part through Battelle Memorial Institute?s prime contract with the US National Institute of Allergy and Infectious Diseases (NIAID) under Contract no. HHSN272200700016I (J. H. K.). This work was also funded in part by Grant 109520 by the UK Department of Health, Public Health England (R. H.). W. M. S. is supported by Funda??o de Amparo ? Pesquisa do Estado de S?o Paulo, Brazil (17/139...
Made available in DSpace on 2018-11-26T15:47:22Z (GMT). No. of bitstreams: 0 Previous issue date: 2018-03-01; FAPEMA; Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq); ANP; FINEP; In this paper, a fast, simple and new alternative method for determination of water content (moisture) in biodiesel using electrochemical impedance spectroscopy (EIS) is developed. The method is based on the sensit...
We report a theoretical study of highly excited O3 in collisions with vibrationally cold OH. Special emphasis is placed on initial vibrational energies of O3 between 9 and 21 kcal mol−1. All calculations have employed the quasiclassical trajectory method and the realistic double many-body expansion potential energy surface for HO4(2A). Many aspects of the title relaxation process are presented. The results indi...
The dynamics of the title five-atom atmospheric reaction is studied by the quasiclassical trajectory method for vibrational states of OH over the range 2 ≤ v ≤ 9 and initial vibrational energies of O3 between 9 and 21 kcal mol-1 using a previously reported double many-body expansion potential energy surface for HO4(2A). The results show that the reaction is controlled by both capture- and barrier-type mechanism...
A quasiclassical trajectory study of the title five-atom reaction is reported for vibrational states of O2 over the range of 12 ≤ v ≤ 27 using a realistic double many body expansion potential energy surface recently reported for HO4(2A). The results indicate that it can be a potential source of ozone in the upper atmosphere.