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Unveiling challenges and opportunities in silicon-based all-solid-state batteri...

Zhao, Mingcai; Zhang, Juan; Costa, Carlos Miguel Silva; Lanceros-Mendez, S.; Zhang, Qi; Wang, Wei

Li-metal and silicon are potential anode materials in all-solid-state Li-ion batteries (ASSBs) due to high specific capacity. However, both materials form gaps at the interface with solid electrolytes (SEs) during charging/discharging, resulting in increased impedance and uneven current density distribution. In this perspective, the different mechanisms of formation of these gaps are elaborated in detail. For L...


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