Author(s): Oliveira, Marcelo R. L. ; Perpetuo, Genivaldo J. ; Janczak, Jan ; Rubinger, Mayura M. M.
Date: 2018
Origin: Oasisbr
Subject(s): Dithiocarbimate; Trithiocarbimate; Zinc complexes; Crystal structure; Dithiocarbimate; Dithiocarbimate; Trithiocarbimate; Trithiocarbimate; Zinc complexes; Zinc complexes; Crystal structure; Crystal structure
Two new zinc(II)-complexes, dithiocarbimato (Ph4P)2[Zn(CH3SO2N=CS2)2] (1) and trithiocarbimato (Ph4P)2[Zn(CH3SO2N=CS3)2] (2), were obtained in the crystalline form by the reaction of potassium N-methylsulfonyldithiocarbimate (RSO2N=CS2K2) with zinc(II) acetate dihydrate and tetraphenylphosphonium chloride in dimethylformamide. Both complexes crystallize in the monoclinic system. The central Zn(II) ion has a distorted tetrahedral coordination in both compounds. In 1 the dithiocarbimato ligand coordinates via two S atoms while in 2 the trithiocarbimato ligand coordinates via S and N atoms. Both complexes were also characterized by IR, 1 H NMR and 13C NMR spectroscopies. Compound 2 is the first example of a zinc(II)-trithiocarbimato complex.
