Autor(es):
Bartolomeu, Aloisio de Andrade [UNESP] ; Menezes, Manoel Lima de [UNESP] ; Silva Filho, Luiz Carlos da [UNESP]
Data: 2015
Identificador Persistente: http://hdl.handle.net/11449/117467
Origem: Oasisbr
Assunto(s): niobium pentachloride; Lewis acid; one-pot condensation; 14-aryl-14H-dibenzo[a,j]xanthene; derivatives; niobium pentachloride; niobium pentachloride; Lewis acid; Lewis acid; one-pot condensation; one-pot condensation; 14-aryl-14H-dibenzo[a,j]xanthene; 14-aryl-14H-dibenzo[a,j]xanthene; derivatives; derivatives
Descrição
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
Pro-Reitoria de Pesquisa da UNESP (PROPe-UNESP)
A simple and efficient procedure for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives through one-pot condensation of 2-naphthol with aryl aldehydes in the presence of niobium pentachloride is described. The reactions were carried out using 25 mole % of NbCl5, at ambient temperature, and in acceptable reaction times, affording excellent yields of the products.
Sao Paulo State Univ UNESP, Fac Sci, Dept Chem, LaOSP, BR-17033360 Sao Paulo, Brazil
Sao Paulo State Univ UNESP, Fac Sci, Dept Chem, LaOSP, BR-17033360 Sao Paulo, Brazil
FAPESP: 12/23821-7
FAPESP: 13/08697-0