Author(s):
Alfredo Cardenas-Riojas, Andy ; Wong, Ademar [UNESP] ; Sotomayor, Maria Del Pilar T. [UNESP] ; La Rosa-Toro, Adolfo ; Maria Baena-Moncada, Angelica
Date: 2019
Persistent ID: http://hdl.handle.net/11449/186217
Origin: Oasisbr
Subject(s): hierarchical porous carbon; sensors; free cyanide; silver sulfide; multiwall carbon nanotubes; hierarchical porous carbon; hierarchical porous carbon; sensors; sensors; free cyanide; free cyanide; silver sulfide; silver sulfide; multiwall carbon nanotubes; multiwall carbon nanotubes
Description
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Two sensors were synthesized for the detection of free cyanide (CN-), based on silver sulfide nanoparticles (Np-Ag2S) supported on Multiwall Carbon Nanotubes (MWCNT) and hierarchical porous carbon (HPC). The Ag2S/HPC400 and Ag2S/MWCNT were characterized by physicochemical techniques such as Raman spectroscopy, X-Ray diffraction (XRD) and Scanning electron microscopy (SEM). These sensors were evaluated against the detection of free cyanide by potentiometry; the stability, reproducibility and linearity of each sensor were determined. A limit of detection of 3.34 mu g L-1 and a limit of quantification of 11.05 mu g L-1 for Ag2S/HPC 400 sensor was obtained; while for the Ag2S/MWCNT sensor a limit of detection and limit of quantification value of 23.17 mu g L-1 and 76.46 mu g L-1 were obtained, respectively. The results show that the presence of carbonaceous materials with a hierarchical structure improves the limits of quantification and detection of the Ag2S/HPC 400 sensor.
Univ Nacl Ingn, Fac Ciencias, Lab Invest Electroquim Aplicada, Av Tupac Amaru 210, Lima, Peru
Univ Estadual Paulista, Inst Quim, BR-14801970 Araraquara, SP, Brazil
Inst Nacl Tecnol Alternat Deteccao, Avaliacao Toxicol & Remocao Micropoluentes & Radi, Araraquara, SP, Brazil
Univ Estadual Paulista, Inst Quim, BR-14801970 Araraquara, SP, Brazil
