Author(s):
Faraco, Thales A. ; De O. X. Silva, Hálice ; Da S. Barud, Hernane ; Maciel, Indhira O. ; Da Silva, Robson R. ; Quirino, Welber G. ; Fragneaud, Benjamin ; Ribeiro, Clóvis A. [UNESP] ; Dos S. Dias, Diógenes ; G. Pandoli, Omar ; Cremona, Marco ; Legnani, Cristiano
Date: 2020
Persistent ID: http://hdl.handle.net/11449/201081
Origin: Oasisbr
Subject(s): Allium cepa L.; biopolymer; biosubstrate; flexible organic light-emitting diode; FOLED; Allium cepa L.; Allium cepa L.; biopolymer; biopolymer; biosubstrate; biosubstrate; flexible organic light-emitting diode; flexible organic light-emitting diode; FOLED; FOLED
Description
Made available in DSpace on 2020-12-12T02:23:37Z (GMT). No. of bitstreams: 0 Previous issue date: 2019-01-01
A new biopolymer obtained from onion pulp (Allium cepa L.) was employed to produce a sustainable substrate for flexible organic light-emitting diodes (FOLEDs). Indium tin oxide (ITO) and SiO2 thin films were deposited by rf-magnetron sputtering onto these biosubstrates to obtain flexible, transparent, and conductive anodes, on top of which FOLEDs were produced. This new biomaterial exhibits an optical transparency of 63% at 550 nm. ITO films were optimized by varying rf power during deposition onto the biopolymers, and their electrical properties are comparable to the those of ITO grown on top of rigid substrates: a carrier concentration of -3.63 × 1021 cm-3 and carrier mobility of 7.72 cm2 V-1 s-1 for the optimized film. Consequently, the sheet resistance and resistivity of this ITO film were 8.92 ω sq-1 and 2.23 × 10-4 ω cm, respectively, hence allowing the production of FOLEDs. The A. cepa L. based FOLED was fabricated using CuPc, β-NPB, and Alq3 as organic layers, and it exhibited a maximum luminance of about 2062 cd m-2 at 16.6 V. The current efficiency reached a maximum value of 2.1 cd A-1 at 85.3 mA cm-2. The obtained results suggest the possibility to use these substrates for innovative biocompatible applications in optoelectronics, such as photodynamic therapy.
Grupo de Nanociência e Nanotecnologia (NANO) Departamento de Física Universidade Federal de Juiz de Fora (UFJF)
Laboratório de Biopolímeros e Biomateriais (BIOPOLMAT) Departamento de Química Universidade de Araraquara (UNIARA)
Instituto de Física de São Carlos Universidade de São Paulo (USP)
Instituto de Química Universidade Estatual Paulista Júlio de Mesquita Filho (UNESP)
BioSmart Nanotechnology
Laboratório de Optoeletrônica Molecular (LOEM) Departamento de Física Pontifícia Universidade Católica Do Rio de Janeiro (PUC-Rio)
Departamento de Química Pontifícia Universidade Católica Do Rio de Janeiro (PUC-Rio)
Instituto de Química Universidade Estatual Paulista Júlio de Mesquita Filho (UNESP)
