Autor(es):
Pezza, Helena Redigolo [UNESP] ; Lopes, Cristiane F. Fernandes ; Suárez-Iha, Maria Encarnación V. ; Coichev, Nina
Data: 2014
Identificador Persistente: http://hdl.handle.net/11449/27563
Origem: Oasisbr
Assunto(s): sulfite; catalysed autoxidation; transition metal ions; sulfite; sulfite; catalysed autoxidation; catalysed autoxidation; transition metal ions; transition metal ions
Descrição
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
The oxidation process of sulfur (IV) species (SO2, HSO3- e SO32-) by oxygen, catalysed by trace metal ion and complexes, can play an important role in atmospheric, analytical and bioinorganic chemistry. An overview of the most important reactions in these fields is presented. A fascinating redox cycling of the metal ions and complexes during such autoxidation process was revealed by the combination of kinetics and coordination chemistry studies.
Universidade Estadual Paulista
Universidade de São Paulo
Universidade Estadual Paulista