Publicação
New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer
| Resumo: | Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments. |
|---|---|
| Autores principais: | Vilas-Boas, Miguel |
| Outros Autores: | Freire, Cristina; Castro, Baltazar de; Christensen, Paul A.; Hillman, A. Robert |
| Ano: | 1997 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Instituto Politécnico de Bragança |
| Idioma: | inglês |
| Origem: | Biblioteca Digital do IPB |
| _version_ | 1867173073958993920 |
|---|---|
| author | Vilas-Boas, Miguel |
| author2 | Freire, Cristina Castro, Baltazar de Christensen, Paul A. Hillman, A. Robert |
| author2_role | author author author author |
| author_facet | Vilas-Boas, Miguel Freire, Cristina Castro, Baltazar de Christensen, Paul A. Hillman, A. Robert |
| author_role | author |
| contributor_name_str_mv | Biblioteca Digital do IPB |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Vilas-Boas, Miguel\",\"Person.identifier.orcid\":\"0000-0002-8665-5280\"},{\"Person.name\":\"Freire, Cristina\"},{\"Person.name\":\"Castro, Baltazar de\"},{\"Person.name\":\"Christensen, Paul A.\"},{\"Person.name\":\"Hillman, A. Robert\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | Biblioteca Digital do IPB |
| datacite.creators.creator.creatorName.fl_str_mv | Vilas-Boas, Miguel Freire, Cristina Castro, Baltazar de Christensen, Paul A. Hillman, A. Robert |
| datacite.date.Accepted.fl_str_mv | 1997-01-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2011-07-18T14:44:23Z |
| datacite.date.embargoed.fl_str_mv | 2011-07-18T14:44:23Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.titles.title.fl_str_mv | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| dc.contributor.none.fl_str_mv | Biblioteca Digital do IPB |
| dc.creator.none.fl_str_mv | Vilas-Boas, Miguel Freire, Cristina Castro, Baltazar de Christensen, Paul A. Hillman, A. Robert |
| dc.date.Accepted.fl_str_mv | 1997-01-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2011-07-18T14:44:23Z |
| dc.date.embargoed.fl_str_mv | 2011-07-18T14:44:23Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10198/5892 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | A |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.title.fl_str_mv | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://bibliotecadigital.ipb.pt/bitstreams/fb7a455c-2af7-470b-a256-f02709068cc7/download |
| id | ipb_bf92da1dc585b8095465c706fc4f3fdc |
| identifier.url.fl_str_mv | http://hdl.handle.net/10198/5892 |
| instacron_str | ipb |
| institution | Instituto Politécnico de Bragança |
| instname_str | Instituto Politécnico de Bragança |
| language | eng |
| network_acronym_str | ipb |
| network_name_str | Biblioteca Digital do IPB |
| oai_identifier_str | oai:bibliotecadigital.ipb.pt:10198/5892 |
| organization_str_mv | urn:organizationAcronym:ipb |
| person_str_mv | Vilas-Boas, Miguel Vilas-Boas, Miguel https://www.ciencia-id.pt/A918-C6FF-81A4 A918-C6FF-81A4 http://orcid.org/0000-0002-8665-5280 0000-0002-8665-5280 Freire, Cristina Castro, Baltazar de Christensen, Paul A. Hillman, A. Robert |
| publishDate | 1997 |
| publisher.none.fl_str_mv | A |
| reponame_str | Biblioteca Digital do IPB |
| repository_id_str | urn:repositoryAcronym:ipb |
| service_str_mv | urn:repositoryAcronym:ipb |
| spelling | engAporOxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)], in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by ex situ EPR experiments.application/pdfporNew Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymerPersonalVilas-Boas, MiguelDSpacehttp://dspace.org/items/f58280c8-298b-4e4c-9f7c-4517300d3382DSpacehttp://dspace.org/items/f58280c8-298b-4e4c-9f7c-4517300d3382Vilas-BoasMiguelCiência IDhttps://www.ciencia-id.ptA918-C6FF-81A4ORCIDhttp://orcid.org0000-0002-8665-5280Researcher IDhttps://www.researcherid.comI-5949-2013Scopus Author IDhttps://www.scopus.com6602648497Freire, CristinaCastro, Baltazar deChristensen, Paul A.Hillman, A. RobertHostingInstitutionOrganizationalBiblioteca Digital do IPBe-mailmailto:dspace@ipb.ptdspace@ipb.ptISSNIsPartOf0020-1669DOIIsPartOf10.1021/ic970467j2011-07-18T14:44:23Z19971997-01-01T00:00:00ZHandlehttp://hdl.handle.net/10198/5892http://purl.org/coar/access_right/c_abf2open access256798 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://bibliotecadigital.ipb.pt/bitstreams/fb7a455c-2af7-470b-a256-f02709068cc7/downloadInorganic Chemistry3641194129 |
| spellingShingle | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer Vilas-Boas, Miguel |
| status | SINGLETON |
| title | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| title_full | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| title_fullStr | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| title_full_unstemmed | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| title_short | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| title_sort | New Insigths into the structure and properties of electroactive polymer filmes derived from Ni(salen)polymer |
| url | http://hdl.handle.net/10198/5892 |
| visible | 1 |