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Chloride threshold value to initiate reinforcement corrosion in simulated concrete pore solutions: The influence of surface finishing and pH

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Resumo:The influence of steel surface finishing and pH of simulated concrete pore solutions (SCPS) on the chloride threshold value (CTV) was evaluated. Steel samples were analysed, with four different finishes: as received (T), diamond-polished (D), polished (P500) and pre-oxidized (DH). The studies were performed in SCPS with pH values of 11.6 and 13.5, and of different chloride concentrations. The electrochemical behaviour of the samples was assessed using open circuit potential, potentiodynamic polarization curves and scanning vibrating electrode techniques. The surface of the steel samples was observed by optical microscopy and SEM/EDS. The results showed that the samples were ranked D > DH > P500 > T for the CTV after which pitting corrosion occurs. The highest chloride threshold value was found in D samples.
Autores principais:Figueira, R. B.
Outros Autores:Sadovski, Andrei; Melo, Ana P.; Vaz Pereira, Elsa
Assunto:Corrosion Reinforced concrete Chloride threshold value Steel surface
Ano:2017
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Instituto Politécnico de Lisboa
Idioma:inglês
Origem:Repositório Científico do Instituto Politécnico de Lisboa
Descrição
Resumo:The influence of steel surface finishing and pH of simulated concrete pore solutions (SCPS) on the chloride threshold value (CTV) was evaluated. Steel samples were analysed, with four different finishes: as received (T), diamond-polished (D), polished (P500) and pre-oxidized (DH). The studies were performed in SCPS with pH values of 11.6 and 13.5, and of different chloride concentrations. The electrochemical behaviour of the samples was assessed using open circuit potential, potentiodynamic polarization curves and scanning vibrating electrode techniques. The surface of the steel samples was observed by optical microscopy and SEM/EDS. The results showed that the samples were ranked D > DH > P500 > T for the CTV after which pitting corrosion occurs. The highest chloride threshold value was found in D samples.