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Synthesis of novel derivatives of a versatile synthon : 4-amino-3-cyanopyrazole

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Detalhes bibliográficos
Resumo:Diazotisation of substituted arylamines followed by reaction with malononitrile gave substituted arylazomalononitriles. Cyclisation of these intermediates with two carbon sources and base gave the corresponding new 4-amino-3-cyanopyrazoles, in moderate yields. In one case the corresponding oxo-pyrazolopyrimidine was prepared.
Autores principais:Rodrigues, Lígia M.
Outros Autores:Campos, Ana M. F. Oliveira; Kaja, Martin; Hrdina, Radim
Assunto:Cyanopyrazole Oxo-pyrazolopyrimidine Pyrazole
Ano:2004
País:Portugal
Tipo de documento:comunicação em conferência
Tipo de acesso:acesso aberto
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
Descrição
Resumo:Diazotisation of substituted arylamines followed by reaction with malononitrile gave substituted arylazomalononitriles. Cyclisation of these intermediates with two carbon sources and base gave the corresponding new 4-amino-3-cyanopyrazoles, in moderate yields. In one case the corresponding oxo-pyrazolopyrimidine was prepared.