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Cryptolepine analogues containing basic aminoalkyl side-chains at C-11

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Resumo:A series of cryptolepine derivatives has been synthesized through the incorporation of short basic side-chains in the C-11 position of the 10H-indolo[3,2-b] quinoline scaffold. Their antiplasmodial activity was evaluated in vitro against the chloroquine resistant Plasmodium falciparum W2 strain, showing IC50 values between 22 and 184 nM, while their cytotoxicity was assessed using HUVEC cells, revealing three compounds with a selectivity ratio higher than 10. The most selective of these derivatives, 4d, with a selectivity ratio of 46, was also the least cytotoxic of the series. (c) 2008 Elsevier Ltd. All rights reserved.
Autores principais:Lavrado, Joao
Outros Autores:Paulo, Alexandra; Gut, Jiri; Rosenthal, Philip J.; Moreira, Rui
Assunto:Chemistry, Medicinal Chemistry, Organic
Ano:2008
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso a metadados
Instituição associada:Universidade de Lisboa
Idioma:inglês
Origem:Repositório da Universidade de Lisboa
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author Lavrado, Joao
author2 Paulo, Alexandra
Gut, Jiri
Rosenthal, Philip J.
Moreira, Rui
author2_role author
author
author
author
author_facet Lavrado, Joao
Paulo, Alexandra
Gut, Jiri
Rosenthal, Philip J.
Moreira, Rui
author_role author
contributor_name_str_mv Repositório Científico de Acesso Aberto da ULisboa
country_str PT
creators_json_txt [{\"Person.name\":\"Lavrado, Joao\"},{\"Person.name\":\"Paulo, Alexandra\"},{\"Person.name\":\"Gut, Jiri\"},{\"Person.name\":\"Rosenthal, Philip J.\"},{\"Person.name\":\"Moreira, Rui\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Repositório Científico de Acesso Aberto da ULisboa
datacite.creators.creator.creatorName.fl_str_mv Lavrado, Joao
Paulo, Alexandra
Gut, Jiri
Rosenthal, Philip J.
Moreira, Rui
datacite.date.Accepted.fl_str_mv 2008-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2015-12-30T10:18:31Z
datacite.date.embargoed.fl_str_mv 2015-12-30T10:18:31Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_14cb
datacite.subjects.subject.fl_str_mv Chemistry, Medicinal
Chemistry, Organic
datacite.titles.title.fl_str_mv Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
Synthesis, antiplasmodial activity, and cytotoxicity
dc.contributor.none.fl_str_mv Repositório Científico de Acesso Aberto da ULisboa
dc.creator.none.fl_str_mv Lavrado, Joao
Paulo, Alexandra
Gut, Jiri
Rosenthal, Philip J.
Moreira, Rui
dc.date.Accepted.fl_str_mv 2008-01-01T00:00:00Z
dc.date.available.fl_str_mv 2015-12-30T10:18:31Z
dc.date.embargoed.fl_str_mv 2015-12-30T10:18:31Z
dc.identifier.none.fl_str_mv http://hdl.handle.net/10451/21632
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv PERGAMON-ELSEVIER SCIENCE LTD
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_14cb
dc.subject.none.fl_str_mv Chemistry, Medicinal
Chemistry, Organic
dc.title.fl_str_mv Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
Synthesis, antiplasmodial activity, and cytotoxicity
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description A series of cryptolepine derivatives has been synthesized through the incorporation of short basic side-chains in the C-11 position of the 10H-indolo[3,2-b] quinoline scaffold. Their antiplasmodial activity was evaluated in vitro against the chloroquine resistant Plasmodium falciparum W2 strain, showing IC50 values between 22 and 184 nM, while their cytotoxicity was assessed using HUVEC cells, revealing three compounds with a selectivity ratio higher than 10. The most selective of these derivatives, 4d, with a selectivity ratio of 46, was also the least cytotoxic of the series. (c) 2008 Elsevier Ltd. All rights reserved.
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id ul_0a7e9c8e02a3279cd8d3f958ea55becd
identifier.url.fl_str_mv http://hdl.handle.net/10451/21632
instacron_str ul
institution Universidade de Lisboa
instname_str Universidade de Lisboa
language eng
network_acronym_str ul
network_name_str Repositório da Universidade de Lisboa
oai_identifier_str oai:repositorio.ulisboa.pt:10451/21632
organization_str_mv urn:organizationAcronym:ul
person_str_mv Lavrado, Joao
Paulo, Alexandra
Gut, Jiri
Rosenthal, Philip J.
Moreira, Rui
publishDate 2008
publisher.none.fl_str_mv PERGAMON-ELSEVIER SCIENCE LTD
reponame_str Repositório da Universidade de Lisboa
repository_id_str urn:repositoryAcronym:ul
service_str_mv urn:repositoryAcronym:ul
spelling engPERGAMON-ELSEVIER SCIENCE LTDA series of cryptolepine derivatives has been synthesized through the incorporation of short basic side-chains in the C-11 position of the 10H-indolo[3,2-b] quinoline scaffold. Their antiplasmodial activity was evaluated in vitro against the chloroquine resistant Plasmodium falciparum W2 strain, showing IC50 values between 22 and 184 nM, while their cytotoxicity was assessed using HUVEC cells, revealing three compounds with a selectivity ratio higher than 10. The most selective of these derivatives, 4d, with a selectivity ratio of 46, was also the least cytotoxic of the series. (c) 2008 Elsevier Ltd. All rights reserved.Cryptolepine analogues containing basic aminoalkyl side-chains at C-11Synthesis, antiplasmodial activity, and cytotoxicityLavrado, JoaoPaulo, AlexandraGut, JiriRosenthal, Philip J.Moreira, RuiHostingInstitutionOrganizationalRepositório Científico de Acesso Aberto da ULisboae-mailmailto:repositorio@reitoria.ulisboa.ptrepositorio@reitoria.ulisboa.ptISSNIsPartOf0960-894XDOIIsPartOfhttp://dx.doi.org/10.1016/j.bmcl.2008.01.0152015-12-30T10:18:31Z20082008-01-01T00:00:00ZHandlehttp://hdl.handle.net/10451/21632http://purl.org/coar/access_right/c_14cbmetadata only accessChemistry, MedicinalChemistry, Organicliteraturehttp://purl.org/coar/resource_type/c_6501journal articleBIOORGANIC & MEDICINAL CHEMISTRY LETTERSVol. 1813781381
spellingShingle Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
Lavrado, Joao
Chemistry, Medicinal
Chemistry, Organic
status SINGLETON
subject.fl_str_mv Chemistry, Medicinal
Chemistry, Organic
title Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
title_full Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
title_fullStr Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
title_full_unstemmed Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
title_short Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
title_sort Cryptolepine analogues containing basic aminoalkyl side-chains at C-11
topic Chemistry, Medicinal
Chemistry, Organic
topic_facet Chemistry, Medicinal
Chemistry, Organic
url http://hdl.handle.net/10451/21632
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