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Characterization of flavonoid and naphthopyranone derivatives from Eriocaulon ligulatum using liquid chromatography tandem mass spectrometry


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Liquid chromatography-electrospray ionization multistage ion trap mass spectrometry (LC-ESI-IT-MSn) was used to analyze the secondary metabolites in the methanol extract of the capitulae of Eriocaulon ligulatum. The major components were monoand diglycosides of flavonoids and naphthopyranones. Eleven compounds, including four new flavonol glycosides, were identified based on their fragmentation patterns in MS experiments and on NMR analysis of the isolated compounds. The described data may contribute to a better understanding of the taxonomic classification of the Eriocaulaceae family.

São Paulo State University - UNESP Institute of Chemistry Organic Chemistry Department, CP 355, CEP 14800-900, Araraquara, SP

Centro di Spettrometria di Massa Proteomica e Biomolecolare Istituto di Scienze dell'Alimentazione del CNR, Via Roma, 52 a/c, 83100, Avellino

Università degli Studi di Salerno Dipartimento di Scienze Farmaceutiche, via Ponte Don Melillo, 84084 Fisciano (SA)

São Paulo State University - UNESP Institute of Chemistry Organic Chemistry Department, CP 355, CEP 14800-900, Araraquara, SP

Document Type Journal article
Language English
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