Autor(es):
Barbosa, S. G. ; Peixoto, L. ; Meulman, Brendo ; Alves, M. M. ; Pereira, M. A.
Data: 2016
Identificador Persistente: https://hdl.handle.net/1822/41596
Origem: RepositóriUM - Universidade do Minho
Projeto/bolsa:
info:eu-repo/grantAgreement/FCT/5876/147337/PT;
info:eu-repo/grantAgreement/FCT/5876-PPCDTI/126270/PT
;
info:eu-repo/grantAgreement/FCT/COMPETE/126270/PT;
Assunto(s): Human Urine; Phosphorus recovery; Magnesium sources; Stirring speed; Struvite crystal size; Science & Technology
Descrição
Supplementary data associated with this article can be found, in the online version, at: http://dx.doi.org/10.1016/j.cej.2016.03.148.
Phosphorus recycling and recovery has received special attention due to its non-replaceable and non-renewability. Phosphorus recovery from human urine in the form of struvite crystals is a potential alternative source. In this work, the efficiency of struvite precipitation from source separated human urine and struvite crystals size were analyzed using three different Mg2+ sources (MgCl2, Mg(OH)2 and MgO), individually evaluated using a statistical design of experiments to assess the combined effect of Mg2+:P molar ratio (1:1, 1.5:1 and 2:1) and stirring speed (30, 45 and 60 rpm). Formation of struvite crystals was confirmed by X-ray Diffraction (XRD) and scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS). Using the optimal conditions determined, MgO as Mg2+ source at 2:1 molar ratio and a stirring speed of 30 rpm, 99% of P was recovered as struvite crystals with a size of 50 to 100 m.
This project has received funding from the European Union’s Seventh Programme for research, technological development and demonstration under grant agreement No. 308535. The authors also acknowledge the Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UID/BIO/04469/2013 unit, COMPETE 2020 (POCI-01-0145-FEDER-006684) and the project RECI/BBB-EBI/0179/2012 (FCOMP-01-0124-FEDER-027462).
