Detalhes do Documento

Separation of Branched Alkane Feeds with Metal-Organic Frameworks

Autor(es): Henrique, Adriano ; Brântuas, Pedro ; Zafanelli, Lucas F.A.S. ; Aly, Ezzeldin ; Rodrigues, Alírio ; Maurin, Guillaume ; Serre, Christian ; Silva, José A.C.

Data: 2024

Identificador Persistente: http://hdl.handle.net/10198/31037

Origem: Biblioteca Digital da UPB

Projeto/bolsa: info:eu-repo/grantAgreement/FCT/9471 - RIDTI/PTDC/QEQ-PRS/3599/2014/PT; info:eu-repo/grantAgreement/FCT//SFRH/BD/148525/2019/PT; info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB/00690/2020/PT; info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP/00690/2020/PT; info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA/P/0045/2020/PT; info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB/50020/2020/PT; info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP/50020/2020/PT;

Assunto(s): RON improvement of gasoline; Pentane and hexane isomers separation by adsorption; Metal-Organic Frameworks (MOFs)

Descrição

The production of high-quality gasoline is currently achieved through the Total Isomerization Process that separates n/iso-paraffins in the pentane (C5) and hexane (C6) range while not reaching the ultimate goal of a research octane number (RON) higher than 92. This work demonstrates two promising alternatives/strategies using metal-organic frameworks (MOF) that lead to a novel adsorptive separation process to overcome this limitation. Here, the efficient discrimination of C5/C6 alkane isomers into valuable fractions of high RON (HRON – 2,3-dimethylbutane (23DMB; RON 105), 2,2-dimethylbutane (22DMB; RON 94), and isopentane (iC5; RON 93.5)) and low RON (LRON – n-pentane (nC5; RON 61.7), (nC6; RON 30), 2-methylpentane (2MP; RON 74.5), and 3-methylpentane (3MP; RON 75.5)) compounds is achieved.

Tipo de Documento Póster em conferência
Idioma Inglês
Contribuidor(es) Biblioteca Digital da UPB
Licença CC

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Separation of Branched Alkane Feeds with Metal-Organic Frameworks

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